Investigation of Hydrogen Sorption-Desorption Processes at Gas-Phase Hydrogenation and Defects Formation in Titanium by Means of Electron-Positron Annihilation Techniques; Defect and Diffusion Forum; Vol. 373 : Positron Annihilation - ICPA-17
| Parent link: | Defect and Diffusion Forum: Scientific Journal Vol. 373 : Positron Annihilation - ICPA-17.— 2016.— [P. 317-323] |
|---|---|
| Institutionella upphovsmän: | Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра общей физики (ОФ), Национальный исследовательский Томский политехнический университет (ТПУ) Энергетический институт (ЭНИН) Кафедра атомных и тепловых электростанций (АТЭС) |
| Övriga upphovsmän: | Volokitina T. L. Tatiana Leonidovna, Laptev R. S. Roman Sergeevich, Kudiyarov V. N. Victor Nikolaevich, Gvozdyakov D. V. Dmitry Vasilievich, Babikhina M. N. Mariya Nikolaevna |
| Sammanfattning: | Title screen The results of hydrogen sorption and desorption processes investigation at commercially pure titanium alloy during hydrogenation at gas atmosphere are shown in this article. Titanium alloy hydrogenation at temperatures 350, 450 and 550 °C leads to d-hydrides formation in samples’ volume. Hydrogen sorption rates were calculated on the linear parts of sorption curves and equal to 0.15·10-4 wt%/s at 350 °C, 0.86·10-4 wt%/s at 450 °C, 1.55·10-4 wt%/s at 550 °C. Phase transition in titanium-hydrogen system during thermally stimulated hydrogen desorption investigation by the means of short-wave diffraction of synchrotron radiation shows hydrides dissociation until 520-530 °C. Then a-[b] transition takes place until 690-720 °C and at this temperatures the phase transformation ends and additional hydrogen desorption peak appears in thermally stimulated hydrogen desorption curve. Defect structure at different hydrogen concentration investigation by the means of electron-positron annihilation techniques shows that hydrogen penetration into titanium leads to crystal lattice expansion. It initiates vacancy-type defects formation which reacts with hydrogen and forms defect-hydrogen complexes. Режим доступа: по договору с организацией-держателем ресурса |
| Språk: | engelska |
| Publicerad: |
2016
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| Ämnen: | |
| Länkar: | http://dx.doi.org/10.4028/www.scientific.net/DDF.373.317 |
| Materialtyp: | Elektronisk Bokavsnitt |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655748 |
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