Optimizing the catalyst circulation ratio in a reformer with a moving bed via a combination of real and computational experiments; Catalysis in Industry; Vol. 4, iss. 4

Optimizing the catalyst circulation ratio in a reformer with a moving bed via a combination of real and computational experiments; Catalysis in Industry; Vol. 4, iss. 4

Bibliographic Details
Parent link:Catalysis in Industry: Scientific Journal
Vol. 4, iss. 4.— 2012.— [P. 284-291]
Other Authors: Gyngazova M. S. Mariya Sergeevna, Chekantsev N. V. Nikita Vitalievich, Korolenko M. V. Mikhail Vladimirovich, Ivanchina E. D. Emilia Dmitrievna, Kravtsov A. V. Anatoly Vasilyevich
Summary:Title screen
During the operation of continuous catalyst regeneration reformers, the problem of optimizing the catalyst circulation ratio in the reactor-regenerator system arises. This problem is solved by a combination of real and computational experiments to investigate the regularities of coking on a catalyst’s surface. Based on TGA results for industrial Pt-Sn/?-Al2O3 catalyst, it is concluded that amorphous coke is formed on the catalyst’s surface during reforming, its quantity at the reactor block outlet being 4–6%, depending on the feed composition and technological parameters of the process. The specific surface of samples is 152 m2/g for the fresh catalyst, 140 m2/g after regeneration, and 118 m2/g at the reactor outlet, which correlates with the quantity of coke on the surface of samples. Mathematical analysis of the coking processes in a reformer with a moving bed show that the catalyst circulation ratio must be maintained in the range of 0.008–0.010 m3/m3 to increase the operating efficiency of an industrial unit. Maintaining optimal conditions enables us to control the coking process, keeping coke concentration as low as possible and the catalyst specific surface as high as possible.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2012
Subjects:
электронный ресурс
труды учёных ТПУ
катализаторы
риформинг
реакторы
оптимизация
Online Access:http://dx.doi.org/10.1134/S2070050412040083
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655734

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