Deformation mechanism of the explosive degradation of heavy metal azides under pulsed treatments
| Parent link: | High Energy Chemistry.— , 2000- Vol. 40, iss. 4.— 2006.— [P. 218-223] |
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| Andre forfattere: | , , , , |
| Summary: | Title screen The experimental results on the kinetics of explosive degradation of heavy metal azides by the action of nanosecond laser and electron-beam pulses and by the impact of accelerated microparticles are reported. It was found that, basically, the kinetics of the processes was qualitatively and quantitatively similar under the action of all the above factors. A local lattice deformation was the overall result of initiation by all the above factors. A theoretical analysis of the dependence of the electronic structure and electron density of a crystal on the degree of lattice deformation demonstrated that the lattice deformation resulted in a redistribution of bonds between atoms within the anion and between atoms of neighboring anions. A possible structural mechanism for the initiation of the primary reaction is discussed. Режим доступа: по договору с организацией-держателем ресурса |
| Sprog: | engelsk |
| Udgivet: |
2006
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| Fag: | |
| Online adgang: | https://link.springer.com/article/10.1134%2FS0018143906040047?LI=true |
| Format: | Electronisk Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655595 |
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| 200 | 1 | |a Deformation mechanism of the explosive degradation of heavy metal azides under pulsed treatments |f V. M. Lisitsyn [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 21 tit.] | ||
| 330 | |a The experimental results on the kinetics of explosive degradation of heavy metal azides by the action of nanosecond laser and electron-beam pulses and by the impact of accelerated microparticles are reported. It was found that, basically, the kinetics of the processes was qualitatively and quantitatively similar under the action of all the above factors. A local lattice deformation was the overall result of initiation by all the above factors. A theoretical analysis of the dependence of the electronic structure and electron density of a crystal on the degree of lattice deformation demonstrated that the lattice deformation resulted in a redistribution of bonds between atoms within the anion and between atoms of neighboring anions. A possible structural mechanism for the initiation of the primary reaction is discussed. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t High Energy Chemistry |d 2000- | ||
| 463 | |t Vol. 40, iss. 4 |v [P. 218-223] |d 2006 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a исследование | |
| 610 | 1 | |a лазерное излучение | |
| 610 | 1 | |a электронное излучение | |
| 701 | 1 | |a Lisitsyn |b V. M. |c physicist |c Russian physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1939- |g Viktor Mikhailovich |3 (RuTPU)RU\TPU\pers\28330 |9 13239 | |
| 701 | 1 | |a Zhuravlev |b Yu. N. | |
| 701 | 1 | |a Oleshko |b V. I. |c specialist in the field of lightning engineering |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1948- |g Vladimir Ivanovich |3 (RuTPU)RU\TPU\pers\33783 |9 17381 | |
| 701 | 1 | |a Fedorov |b D. G. | |
| 701 | 1 | |a Tsipilev |b V. P. |c specialist in the field of lightning engineering |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1940- |g Vladimir Papilovich |3 (RuTPU)RU\TPU\pers\33782 |9 17380 | |
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