Electrocatalytic Oxidation of Hydrogen Peroxide on the Graphite Electrode Based on Silver Nanoparticles

Detalles Bibliográficos
Parent link:Key Engineering Materials: Scientific Journal
Vol. 743 : High Technology: Research and Applications (HTRA 2016).— 2017.— [P. 287-291]
Autor Corporativo: Национальный исследовательский Томский политехнический университет (ТПУ) Институт физики высоких технологий (ИФВТ) Кафедра общей химии и химической технологии (ОХХТ)
Otros Autores: Perevezentseva D. O. Dariya Olegovna, Gorchakov E. Eduard, Fedotova D. Daria, Bimatov V. Vladimir, Triphonova E. P. Evgenya Petrovna
Sumario:Title screen
It was established that the silver nanoparticles (AgNPs) in an equimolar ratio have the highest electrochemical activity on a graphite electrode (GE) surface in an alkaline medium. The electrocatalytic oxidation mechanism of hydrogen peroxide on the GE surface was proposed. We detected an additional maximum at E=0.3 V on the cathodic branch of the cyclic curve in the potential range from +2.0 to -1.0 V. The appearance of this maximum indicates the reduction of hydrogen peroxide generated during AgNPs electrooxidation in the potential range from -1.0 to +2.0 V.
Режим доступа: по договору с организацией-держателем ресурса
Lenguaje:inglés
Publicado: 2017
Materias:
Acceso en línea:http://dx.doi.org/10.4028/www.scientific.net/KEM.743.287
Formato: Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=655474

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200 1 |a Electrocatalytic Oxidation of Hydrogen Peroxide on the Graphite Electrode Based on Silver Nanoparticles  |f D. O. Perevezentseva [et al.] 
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300 |a Title screen 
330 |a It was established that the silver nanoparticles (AgNPs) in an equimolar ratio have the highest electrochemical activity on a graphite electrode (GE) surface in an alkaline medium. The electrocatalytic oxidation mechanism of hydrogen peroxide on the GE surface was proposed. We detected an additional maximum at E=0.3 V on the cathodic branch of the cyclic curve in the potential range from +2.0 to -1.0 V. The appearance of this maximum indicates the reduction of hydrogen peroxide generated during AgNPs electrooxidation in the potential range from -1.0 to +2.0 V. 
333 |a Режим доступа: по договору с организацией-держателем ресурса 
461 0 |0 (RuTPU)RU\TPU\network\11477  |t Key Engineering Materials  |o Scientific Journal 
463 0 |0 (RuTPU)RU\TPU\network\21014  |t Vol. 743 : High Technology: Research and Applications (HTRA 2016)  |o The V International Science and Engineering Conference, Decembe 5-7, 2016, Tomsk, Russia  |o [proceedings]  |f National Research Tomsk Polytechnic University (TPU) ; eds. G. E. Osokin ; E. A. Kulinich  |v [P. 287-291]  |d 2017 
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610 1 |a cyclic voltammetry 
610 1 |a hydrogen peroxide 
610 1 |a silver nanoparticles 
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