Oxidation, bromination, and methylenation of carbazole and (E)-3-(2-phenylethenyl)carbazole with HBr/DMSO; Chemistry of Heterocyclic Compounds; Vol. 28, iss. 11

Xehetasun bibliografikoak
Parent link:Chemistry of Heterocyclic Compounds
Vol. 28, iss. 11.— 1992.— [P. 1260-1263]
Beste egile batzuk: Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Filimonov V. D. Viktor Dmitrievich, Krasnokutskaya E. A . Elena Aleksandrovna, Kovaleva L. F.
Gaia:Title screen
It is shown that oxidation of (E)-3-(2-phenylethenyl)-9-methylcarbazole with HBr/DMSO leads to the formation of 1-(6-bromo-9-methylcarbazol-3-yl)-2-phenylethane-1,2-dione. In the case of (E)-3-(2-phenylethenyl)carbazole, methylenation occurs with formation of 9,9′-bis[3-(2-phenylethane-1,2-dionyl)-6-bromocarbazolyl]methane in addition to oxidation of the double bond and bromination of the phenyl ring. This reagent can also be successfully used for the preparative bromination and methylenation of certain carbazoles.
Режим доступа: по договору с организацией-держателем ресурса
Hizkuntza:ingelesa
Argitaratua: 1992
Gaiak:
Sarrera elektronikoa:http://dx.doi.org/10.1007/BF00532073
Formatua: Baliabide elektronikoa Liburu kapitulua
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654877
Deskribapena
Gaia:Title screen
It is shown that oxidation of (E)-3-(2-phenylethenyl)-9-methylcarbazole with HBr/DMSO leads to the formation of 1-(6-bromo-9-methylcarbazol-3-yl)-2-phenylethane-1,2-dione. In the case of (E)-3-(2-phenylethenyl)carbazole, methylenation occurs with formation of 9,9′-bis[3-(2-phenylethane-1,2-dionyl)-6-bromocarbazolyl]methane in addition to oxidation of the double bond and bromination of the phenyl ring. This reagent can also be successfully used for the preparative bromination and methylenation of certain carbazoles.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1007/BF00532073