Difficulties with the Determination of Mercury in Foodstuffs by Stripping Voltammetry

Bibliografiset tiedot
Parent link:Journal of Analytical Chemistry
Vol. 59, iss. 5.— 2004.— [P. 468–473]
Muut tekijät: Batalova V. N., Zakharova E. A. Elsa Arminana, Slepchenko G. B. Galina Borisovna, Malygina M. V.
Yhteenveto:Title screen
The main problems with the determination of mercury in foodstuffs by stripping voltammetry were analyzed. The conditions for obtaining the analytical signal from mercury(II) at a gold-graphite electrode and for reducing the effect of interfering substances were refined. A simplified procedure for the preparation of foodstuff samples by the chemical (HNO3 + H2O2) and photochemical oxidation of samples was proposed. The determination conditions were optimized by the fractional factorial design of the experiments. It was shown that a gas-discharge XeBr excilamp can be used as an alternative to a mercury quartz lamp in the sample preparation of foodstuffs. The conditions for reducing the blank experiment and its contribution to the results of determination were considered.
Режим доступа: по договору с организацией-держателем ресурса
Julkaistu: 2004
Aiheet:
Linkit:http://dx.doi.org/10.1023/B:JANC.0000026240.78768.80
Aineistotyyppi: Elektroninen Kirjan osa
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654849

MARC

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200 1 |a Difficulties with the Determination of Mercury in Foodstuffs by Stripping Voltammetry  |f V. N. Batalova [et al.] 
203 |a Text  |c electronic 
300 |a Title screen 
320 |a [References: p. 473 (18 tit.)] 
330 |a The main problems with the determination of mercury in foodstuffs by stripping voltammetry were analyzed. The conditions for obtaining the analytical signal from mercury(II) at a gold-graphite electrode and for reducing the effect of interfering substances were refined. A simplified procedure for the preparation of foodstuff samples by the chemical (HNO3 + H2O2) and photochemical oxidation of samples was proposed. The determination conditions were optimized by the fractional factorial design of the experiments. It was shown that a gas-discharge XeBr excilamp can be used as an alternative to a mercury quartz lamp in the sample preparation of foodstuffs. The conditions for reducing the blank experiment and its contribution to the results of determination were considered. 
333 |a Режим доступа: по договору с организацией-держателем ресурса 
461 |t Journal of Analytical Chemistry 
463 |t Vol. 59, iss. 5  |v [P. 468–473]  |d 2004 
610 1 |a труды учёных ТПУ 
610 1 |a электронный ресурс 
610 1 |a вольтамперометрия 
610 1 |a пищевые продукты 
610 1 |a ртуть 
610 1 |a анализ 
610 1 |a определение 
701 1 |a Batalova  |b V. N. 
701 1 |a Zakharova  |b E. A.  |c chemist  |c senior research fellow at the Tomsk Polytechnic University, candidate of chemical Sciences  |f 1938-  |g Elsa Arminana  |3 (RuTPU)RU\TPU\pers\33332 
701 1 |a Slepchenko  |b G. B.  |c Chemist  |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences  |f 1956-  |g Galina Borisovna  |3 (RuTPU)RU\TPU\pers\33018  |9 16858 
701 1 |a Malygina  |b M. V. 
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