Oligogermanes Containing Only Electron-Withdrawing Substituents: Synthesis and Properties
| Parent link: | Organometallics Vol. 36, iss. 2.— 2017.— [P. 298–309] |
|---|---|
| Ente Autore: | |
| Altri autori: | , , , , , , , , , |
| Riassunto: | Title screen A series of germanes Ar3GeX, containing electron-withdrawing substituents [Ar = p-FC6H4, 1a–d, 1a (X = Cl), 1b (X = Br), 1c (X = H), 1d (X = NMe2); p-F3CC6H4, 2a–d, 2a (X = Cl), 2b (X = Br), 2c (X = H), 2d (X = NMe2)], was synthesized and used to prepare symmetrical digermanes Ar3Ge–GeAr3, (p-FC6H4)3GeGe(C6H4F-p)3 (3), and (p-F3CC6H4)3GeGe(C6H4CF3-p)3 (4) and trigermane [(p-F3CC6H4)3Ge]2Ge(C6F5)2 (5) by hydrogermolysis reaction. The properties of all compounds were investigated by multinuclear NMR and for oligogermanes by UV/vis and fluorescence spectroscopy, as well as by electrochemical methods. In addition, the molecular structures of 1a, 1b, 2b, 2c, and 3–5 were studied by X-ray diffraction analysis. Compound 5 showed a significantly shifted UV/visible absorption to the red field in comparison with previously described derivatives. Режим доступа: по договору с организацией-держателем ресурса |
| Lingua: | inglese |
| Pubblicazione: |
2017
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| Soggetti: | |
| Accesso online: | http://dx.doi.org/10.1021/acs.organomet.6b00767 |
| Natura: | Elettronico Capitolo di libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654787 |
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| 200 | 1 | |a Oligogermanes Containing Only Electron-Withdrawing Substituents: Synthesis and Properties |f K. V. Zaitsev [at al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 330 | |a A series of germanes Ar3GeX, containing electron-withdrawing substituents [Ar = p-FC6H4, 1a–d, 1a (X = Cl), 1b (X = Br), 1c (X = H), 1d (X = NMe2); p-F3CC6H4, 2a–d, 2a (X = Cl), 2b (X = Br), 2c (X = H), 2d (X = NMe2)], was synthesized and used to prepare symmetrical digermanes Ar3Ge–GeAr3, (p-FC6H4)3GeGe(C6H4F-p)3 (3), and (p-F3CC6H4)3GeGe(C6H4CF3-p)3 (4) and trigermane [(p-F3CC6H4)3Ge]2Ge(C6F5)2 (5) by hydrogermolysis reaction. The properties of all compounds were investigated by multinuclear NMR and for oligogermanes by UV/vis and fluorescence spectroscopy, as well as by electrochemical methods. In addition, the molecular structures of 1a, 1b, 2b, 2c, and 3–5 were studied by X-ray diffraction analysis. Compound 5 showed a significantly shifted UV/visible absorption to the red field in comparison with previously described derivatives. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Organometallics | ||
| 463 | |t Vol. 36, iss. 2 |v [P. 298–309] |d 2017 | ||
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