Oligogermanes Containing Only Electron-Withdrawing Substituents: Synthesis and Properties

Oligogermanes Containing Only Electron-Withdrawing Substituents: Synthesis and Properties

Detalles Bibliográficos
Parent link:Organometallics
Vol. 36, iss. 2.— 2017.— [P. 298–309]
Autor Corporativo: Национальный исследовательский Томский политехнический университет (ТПУ) Юргинский технологический институт (филиал) (ЮТИ) Кафедра сварочного производства (КСП)
Otros Autores: Zaitsev K. V. Kirill Vasiljevich, Lam K. Kevin, Zhaisan Zhanabil, Suleimen Yerlan, Kharcheva A. V. Anna Viktorovna, Tafeenko V. A. Viktor Aleksandrovich, Oprunenko Yu. F. Yuri, Poleshchuk O. Kh. Oleg Khemovich, Lermontova E. K. Elena Khimovna, Churakov A. V.
Sumario:Title screen
A series of germanes Ar3GeX, containing electron-withdrawing substituents [Ar = p-FC6H4, 1a–d, 1a (X = Cl), 1b (X = Br), 1c (X = H), 1d (X = NMe2); p-F3CC6H4, 2a–d, 2a (X = Cl), 2b (X = Br), 2c (X = H), 2d (X = NMe2)], was synthesized and used to prepare symmetrical digermanes Ar3Ge–GeAr3, (p-FC6H4)3GeGe(C6H4F-p)3 (3), and (p-F3CC6H4)3GeGe(C6H4CF3-p)3 (4) and trigermane [(p-F3CC6H4)3Ge]2Ge(C6F5)2 (5) by hydrogermolysis reaction. The properties of all compounds were investigated by multinuclear NMR and for oligogermanes by UV/vis and fluorescence spectroscopy, as well as by electrochemical methods. In addition, the molecular structures of 1a, 1b, 2b, 2c, and 3–5 were studied by X-ray diffraction analysis. Compound 5 showed a significantly shifted UV/visible absorption to the red field in comparison with previously described derivatives.
Режим доступа: по договору с организацией-держателем ресурса
Lenguaje:inglés
Publicado: 2017
Materias:
электронный ресурс
труды учёных ТПУ
синтез
свойства
спектроскопия
электрохимические методы
Acceso en línea:http://dx.doi.org/10.1021/acs.organomet.6b00767
Formato: Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654787
Descripción
Sumario:Title screen
A series of germanes Ar3GeX, containing electron-withdrawing substituents [Ar = p-FC6H4, 1a–d, 1a (X = Cl), 1b (X = Br), 1c (X = H), 1d (X = NMe2); p-F3CC6H4, 2a–d, 2a (X = Cl), 2b (X = Br), 2c (X = H), 2d (X = NMe2)], was synthesized and used to prepare symmetrical digermanes Ar3Ge–GeAr3, (p-FC6H4)3GeGe(C6H4F-p)3 (3), and (p-F3CC6H4)3GeGe(C6H4CF3-p)3 (4) and trigermane [(p-F3CC6H4)3Ge]2Ge(C6F5)2 (5) by hydrogermolysis reaction. The properties of all compounds were investigated by multinuclear NMR and for oligogermanes by UV/vis and fluorescence spectroscopy, as well as by electrochemical methods. In addition, the molecular structures of 1a, 1b, 2b, 2c, and 3–5 were studied by X-ray diffraction analysis. Compound 5 showed a significantly shifted UV/visible absorption to the red field in comparison with previously described derivatives.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1021/acs.organomet.6b00767

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