Iodonium ylides in organic synthesis; ARKIVOC; Vol. 2016
| Parent link: | ARKIVOC Vol. 2016.— 2016.— [P. 342-374] |
|---|---|
| Autor principal: | |
| Autor Corporativo: | |
| Outros Autores: | , |
| Resumo: | Title screen This review summarizes the chemistry of iodonium ylides with emphasis on their synthetic applications. The preparation, structure and chemistry of iodonium ylides of different structural types are overviewed. Iodonium ylides have found synthetic application as efficient carbene precursors,especially useful as reagents for cyclopropanation of alkenes and preparation of heterocyclic compounds. Recently iodonium ylides have been utilized as efficient reagents in the thiotrifluoromethylation and nucleophilic fluorination reactions. |
| Idioma: | inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | http://dx.doi.org/10.3998/ark.5550190.p009.732 |
| Formato: | Recurso Eletrônico Capítulo de Livro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654723 |
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| 200 | 1 | |a Iodonium ylides in organic synthesis |f M. S. Yusubov, A. Yoshimura, V. V. Zhdankin | |
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| 300 | |a Title screen | ||
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| 330 | |a This review summarizes the chemistry of iodonium ylides with emphasis on their synthetic applications. The preparation, structure and chemistry of iodonium ylides of different structural types are overviewed. Iodonium ylides have found synthetic application as efficient carbene precursors,especially useful as reagents for cyclopropanation of alkenes and preparation of heterocyclic compounds. Recently iodonium ylides have been utilized as efficient reagents in the thiotrifluoromethylation and nucleophilic fluorination reactions. | ||
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| 463 | |t Vol. 2016 |v [P. 342-374] |d 2016 | ||
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