Kinetic studies of methanol dehydrogenation. Part I: copper-silica catalysts; Reaction Kinetics, Mechanisms and Catalysis; Vol. 120, iss. 2

Kinetic studies of methanol dehydrogenation. Part I: copper-silica catalysts; Reaction Kinetics, Mechanisms and Catalysis; Vol. 120, iss. 2

書目詳細資料
Parent link:	Reaction Kinetics, Mechanisms and Catalysis Vol. 120, iss. 2.— 2017.— [P. 449–458]
主要作者:	Shelepova E. V. Ekaterina Vladimirovna
企業作者:	Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра физической и аналитической химии (ФАХ)
其他作者:	Ilina L. Yu. Lyudmila, Vedyagin A. A. Aleksey Anatolievich
總結:	Title screen A series of Cu/SiO2 catalysts was prepared using incipient wetness impregnation of silica gel with an aqueous solution of copper nitrate. The copper loading was 5 wt%. After the calcination, the catalyst was reduced in a hydrogen flow at varied temperatures (200, 300, and 400 °C). A conventional fixed bed reactor system was used to study the kinetics of methanol dehydrogenation to methyl formate. Methyl formate decomposition to carbon monoxide and hydrogen was taken into account as a main side reaction. Observable rate constants were determined. The temperature of reductive pretreatment of the catalysts was shown to affect strongly their catalytic behavior in the studied reaction. The highest methyl formate yield was achieved for the sample reduced at 200 °C. An increase of reduction temperature up to 400 °C worsens the selectivity towards the main product in approximately by a factor of 2. The kinetic parameters obtained were used for modelling the process in a tubular reactor. Good agreement of theoretical and experimental data was found. Режим доступа: по договору с организацией-держателем ресурса
語言:	英语
出版:	2017
主題:	электронный ресурс труды учёных ТПУ catalysts kinetics дегидрирование метанол катализаторы
在線閱讀:	http://dx.doi.org/10.1007/s11144-016-1135-1
格式:	電子 Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=654626

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