Heat Capacity of 1D Molecular Chains

Heat Capacity of 1D Molecular Chains

書誌詳細
Parent link:	Journal of Low Temperature Physics.— , 1969- Vol. 187, iss. 1.— 2017.— [P. 113–123]
団体著者:	Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра высшей математики и математической физики (ВММФ)
その他の著者:	Bagatskii M. I. Michail Ivanovich, Barabashko M. S. Maksim Sergeevich, Sumarokov V. V. Vladimir Victorovich, Jezowski A. Andrzej, Stachowiak P. Petro
要約:	Title screen The heat capacity of 1D chains of nitrogen and methane molecules (adsorbed in the outer grooves of bundles of closed-cap single-walled carbon nanotubes) has been studied in the temperature ranges 2–40 and 2–60 K, respectively. The temperature dependence of the heat capacity of 1D chains of nitrogen molecules below 3 K is close to a linear. It was found that the rotational heat capacity of methane molecules is a significant part of the total heat capacity of the chains throughout the whole investigated temperature range, whereas in the case of nitrogen, the librations are significant only above 15 K. The dependence of the heat capacity for methane below 10 K indicates the presence of a Schottky anomaly caused by the tunneling between the lowest energy levels of the CH4CH4 molecule rotational spectra. Characteristic features observed in the temperature dependence of the heat capacity of 1D methane crystals are also discussed. Режим доступа: по договору с организацией-держателем ресурса
出版事項:	2017
主題:	электронный ресурс труды учёных ТПУ heat capacity single-walled carbon nanotube bundles one-dimensional molecular chains тепловая мощность углеродные нанотрубки молекулярные цепи
オンライン･アクセス:	http://dx.doi.org/10.1007/s10909-016-1737-z
フォーマット:	電子媒体図書の章
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=653957

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