Conformer of the peroxynitrite ion formed under photolysis of crystalline alkali nitrates – cis or trans?

Detalhes bibliográficos
Parent link:IOP Conference Series: Materials Science and Engineering
Vol. 168 : Radiation-Thermal Effects and Processes in Inorganic Materials (RTEP2016).— 2017.— [012091, 5 p.]
Autor Corporativo: Национальный исследовательский Томский политехнический университет (ТПУ) Энергетический институт (ЭНИН) Кафедра автоматизации теплоэнергетических процессов (АТП)
Outros Autores: Pak V. Kh., Anan’ev V. A., Dyagileva E. P., Lyrshchikov S. Yu. Sergey Yurievich, Miklin M. B., Rezvova M. A.
Resumo:Title screen
The optical and infrared reflectance spectra of the crystalline powders prepared by co-crystallization of caesium nitrate, nitrite, and peroxynitrite from alkali solution have been studied. We find that the trans conformer forms under photolysis of crystalline pure caesium nitrate. Under its dissolution the trans conformer transforms to the cis conformer.
Idioma:inglês
Publicado em: 2017
Colecção:Technologies and equipment for their implementation
Assuntos:
Acesso em linha:http://dx.doi.org/10.1088/1757-899X/168/1/012091
http://earchive.tpu.ru/handle/11683/37776
Formato: Recurso Electrónico Capítulo de Livro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=653867
Descrição
Resumo:Title screen
The optical and infrared reflectance spectra of the crystalline powders prepared by co-crystallization of caesium nitrate, nitrite, and peroxynitrite from alkali solution have been studied. We find that the trans conformer forms under photolysis of crystalline pure caesium nitrate. Under its dissolution the trans conformer transforms to the cis conformer.
DOI:10.1088/1757-899X/168/1/012091