Synthesis of L-Lactide Supplemented with Stage-wise Analytical Control

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Parent link:Petroleum and Coal
Vol. 58, iss. 5.— 2016.— [P. 561-566]
Korporativní autor: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Další autoři: Krutas D. S. Darjya Sergeevna, Brozek J. Jiri, Benesova V. Vaclava, Zinovyev (Zinovjev, Zinoviev) A. L. Alexey Leonidovich, Novikov V. T. Viktor Timofeevich
Shrnutí:Title screen
L-lactide synthesis from an aqueous solution of L-lactic acid under different conditions in the presence or absence of a catalyst (zinc oxide, stannous octoate or magnesium ethoxide) has been studied. Synthe-sis of L-lactide is accompanied by analytical control. The glass transition temperature of lactic acid oligo-mers, i.e. a product of polycondensation at the first stage of the process, has been investigated using differential scanning calorimetry (DSC). Identification and quantitative determination of lactic acid and L-lactide at different stages of the synthesis have been performed by HPLC. A residual solvent in L-lactide after its recrystallization has been determined by gas chromatographymass spectrometry (GC-MS).
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Jazyk:angličtina
Vydáno: 2016
Témata:
On-line přístup:http://www.vurup.sk/wp-content/uploads/dlm_uploads/2017/07/pc_6_2016_krutas_489cor.pdf
Médium: Elektronický zdroj Kapitola
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=653523

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330 |a L-lactide synthesis from an aqueous solution of L-lactic acid under different conditions in the presence or absence of a catalyst (zinc oxide, stannous octoate or magnesium ethoxide) has been studied. Synthe-sis of L-lactide is accompanied by analytical control. The glass transition temperature of lactic acid oligo-mers, i.e. a product of polycondensation at the first stage of the process, has been investigated using differential scanning calorimetry (DSC). Identification and quantitative determination of lactic acid and L-lactide at different stages of the synthesis have been performed by HPLC. A residual solvent in L-lactide after its recrystallization has been determined by gas chromatographymass spectrometry (GC-MS). 
333 |a Свободный доступ из сети Интернет 
461 |t Petroleum and Coal 
463 |t Vol. 58, iss. 5  |v [P. 561-566]  |d 2016 
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