X-ray diffraction study of α-34S within temperature range 100-363 K; Journal of Structural Chemistry; Vol. 57, iss. 8

X-ray diffraction study of α-34S within temperature range 100-363 K; Journal of Structural Chemistry; Vol. 57, iss. 8

Bibliographic Details
Parent link:Journal of Structural Chemistry
Vol. 57, iss. 8.— 2016.— [P. 1663-1668]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра химической технологии редких, рассеянных и радиоактивных элементов (№ 43) (ХТРЭ)
Other Authors: Gromilov S. A. Sergey Aleksandrovich, Piryazev D. A. Dmitry Aleksandrovich, Egorov N. B. Nikolai Borisovich, Akimov D. V. Dmitry Vasilievich
Summary:Title screen
α-34S has been studied with X-ray crystallography within 100-363 K. Anisotropy of the evolution of the parameters of the orthorhombic unit cell has been examined. The absolute increase in the cell volume is 154 Å3, and the relative one is 4.8%. It has been demonstrated that in the studied range the intramolecular S-S bond lengths are shortened at average by 0.006 Å on heating. At the same time, intermolecular contacts S…S shorter than the sum of van der Waals radii demonstrate average elongation of 0.097 Å.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2016
Subjects:
электронный ресурс
труды учёных ТПУ
рентгеновская кристаллография
кристаллохимия
Online Access:http://dx.doi.org/10.1134/S0022476616080230
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=653440

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