X-ray diffraction study of α-34S within temperature range 100-363 K
| Parent link: | Journal of Structural Chemistry Vol. 57, iss. 8.— 2016.— [P. 1663-1668] |
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| Müşterek Yazar: | |
| Diğer Yazarlar: | , , , |
| Özet: | Title screen α-34S has been studied with X-ray crystallography within 100-363 K. Anisotropy of the evolution of the parameters of the orthorhombic unit cell has been examined. The absolute increase in the cell volume is 154 Å3, and the relative one is 4.8%. It has been demonstrated that in the studied range the intramolecular S-S bond lengths are shortened at average by 0.006 Å on heating. At the same time, intermolecular contacts S…S shorter than the sum of van der Waals radii demonstrate average elongation of 0.097 Å. Режим доступа: по договору с организацией-держателем ресурса |
| Dil: | İngilizce |
| Baskı/Yayın Bilgisi: |
2016
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| Konular: | |
| Online Erişim: | http://dx.doi.org/10.1134/S0022476616080230 |
| Materyal Türü: | Elektronik Kitap Bölümü |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=653440 |
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| 200 | 1 | |a X-ray diffraction study of α-34S within temperature range 100-363 K |f S. A. Gromilov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 11 tit.] | ||
| 330 | |a α-34S has been studied with X-ray crystallography within 100-363 K. Anisotropy of the evolution of the parameters of the orthorhombic unit cell has been examined. The absolute increase in the cell volume is 154 Å3, and the relative one is 4.8%. It has been demonstrated that in the studied range the intramolecular S-S bond lengths are shortened at average by 0.006 Å on heating. At the same time, intermolecular contacts S…S shorter than the sum of van der Waals radii demonstrate average elongation of 0.097 Å. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Structural Chemistry | ||
| 463 | |t Vol. 57, iss. 8 |v [P. 1663-1668] |d 2016 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a рентгеновская кристаллография | |
| 610 | 1 | |a кристаллохимия | |
| 701 | 1 | |a Gromilov |b S. A. |g Sergey Aleksandrovich | |
| 701 | 1 | |a Piryazev |b D. A. |g Dmitry Aleksandrovich | |
| 701 | 1 | |a Egorov |b N. B. |c chemical engineer |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical science |f 1974- |g Nikolai Borisovich |3 (RuTPU)RU\TPU\pers\31207 |9 15403 | |
| 701 | 1 | |a Akimov |b D. V. |c Chemical Engineer |c Engineer of Tomsk Polytechnic University, Postgraduate |f 1988- |g Dmitry Vasilievich |3 (RuTPU)RU\TPU\pers\32661 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет (ТПУ) |b Физико-технический институт (ФТИ) |b Кафедра химической технологии редких, рассеянных и радиоактивных элементов (№ 43) (ХТРЭ) |3 (RuTPU)RU\TPU\col\18733 |
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