X-ray diffraction study of α-34S within temperature range 100-363 K; Journal of Structural Chemistry; Vol. 57, iss. 8
| Parent link: | Journal of Structural Chemistry Vol. 57, iss. 8.— 2016.— [P. 1663-1668] |
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| Ente Autore: | |
| Altri autori: | , , , |
| Riassunto: | Title screen α-34S has been studied with X-ray crystallography within 100-363 K. Anisotropy of the evolution of the parameters of the orthorhombic unit cell has been examined. The absolute increase in the cell volume is 154 Å3, and the relative one is 4.8%. It has been demonstrated that in the studied range the intramolecular S-S bond lengths are shortened at average by 0.006 Å on heating. At the same time, intermolecular contacts S…S shorter than the sum of van der Waals radii demonstrate average elongation of 0.097 Å. Режим доступа: по договору с организацией-держателем ресурса |
| Lingua: | inglese |
| Pubblicazione: |
2016
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| Soggetti: | |
| Accesso online: | http://dx.doi.org/10.1134/S0022476616080230 |
| Natura: | Elettronico Capitolo di libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=653440 |
| Riassunto: | Title screen α-34S has been studied with X-ray crystallography within 100-363 K. Anisotropy of the evolution of the parameters of the orthorhombic unit cell has been examined. The absolute increase in the cell volume is 154 Å3, and the relative one is 4.8%. It has been demonstrated that in the studied range the intramolecular S-S bond lengths are shortened at average by 0.006 Å on heating. At the same time, intermolecular contacts S…S shorter than the sum of van der Waals radii demonstrate average elongation of 0.097 Å. Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.1134/S0022476616080230 |