Effect of Ag loading on the adsorption/desorption properties of ZSM-5 towards toluene; Reaction Kinetics, Mechanisms and Catalysis; Vol. 119, iss. 2

Effect of Ag loading on the adsorption/desorption properties of ZSM-5 towards toluene; Reaction Kinetics, Mechanisms and Catalysis; Vol. 119, iss. 2

Bibliographic Details
Parent link:Reaction Kinetics, Mechanisms and Catalysis
Vol. 119, iss. 2.— 2016.— [P. 620-640]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Энергетический институт (ЭНИН) Кафедра атомных и тепловых электростанций (АТЭС)
Other Authors: Temerev V. L. Victor, Vedyagin A. A. Aleksey Anatolievich, Afonasenko T. N. Tatyana, Iost K. N. Kristina, Kotolevich Yu. S. Yulia, Baltakhinov V. P. Vladimir, Tsyrulnikov P. G. Pavel
Summary:Title screen
A series of Ag-ZSM-5 samples with different Ag loading (0-10 wt%) was prepared via ion exchange. All samples were characterized by similar adsorption behavior towards toluene vapors. The concentration of Ag as well as the nature of Ag species were found to affect strongly the strength of toluene adsorption thus resulting in different profiles of temperature programmed desorption. The water vapors were shown to have a negative effect on adsorption properties of low Ag samples. It was suggested that the increase of Ag loading leads to the appearance of Agnδ+ (n = 2-8) clusters instead of monoatomic Ag+ sites predominantly existed in the case of the samples with low silver loading. It was found experimentally and explained theoretically by means of DFT calculations that these clusters exceed the monoatomic species by the strength of toluene adsorption even in the presence of water vapors. At the same time, SiO2/Al2O3 ratio in Ag-ZSM-5 samples was found to have no significant effect on adsorption/desorption properties of the zeolites.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2016
Subjects:
электронный ресурс
труды учёных ТПУ
толуолы
адсорбция
десорбция
Online Access:http://dx.doi.org/10.1007/s11144-016-1060-3
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=653057

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