A simple protocol for the synthesis of ?-substituted phosphonates

Bibliographic Details
Parent link:Phosphorus, Sulfur, and Silicon and the Related Elements: Scientific Journal.— , 1976-
Vol. 191, iss. 9.— 2016.— [P. 1268-1273]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Other Authors: Wang X. Xing, Cai Yu. Yuan, Chen J. Jian, Verpoort F. V. K. Frensis Valter Kornelius
Summary:Title screen
An efficient, easy-to-handle, and mild substitution reaction approach has been developed for the synthesis of phosphonate derivatives, which are very important in the field of industrial, agricultural, and medicinal chemistry. A large number of nucleophiles, including arylamines, alkylamines, heteroarylamines, primary amines and secondary amines, sulfides, and carbides were attempted to react with ?-tosyloxyphosphonate 1. The reaction proceeded under catalyst-free and neat conditions and the corresponding phosphonates 2 were afforded in good yields.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2016
Subjects:
Online Access:http://dx.doi.org/10.1080/10426507.2016.1167056
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=652452

MARC

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200 1 |a A simple protocol for the synthesis of ?-substituted phosphonates  |f X. Wang [et al.] 
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320 |a [References: p. 1272-1273 (54 tit.)] 
330 |a An efficient, easy-to-handle, and mild substitution reaction approach has been developed for the synthesis of phosphonate derivatives, which are very important in the field of industrial, agricultural, and medicinal chemistry. A large number of nucleophiles, including arylamines, alkylamines, heteroarylamines, primary amines and secondary amines, sulfides, and carbides were attempted to react with ?-tosyloxyphosphonate 1. The reaction proceeded under catalyst-free and neat conditions and the corresponding phosphonates 2 were afforded in good yields. 
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