Control of interpenetration via in situ lithium incorporation in MOFs and their gas adsorption properties and selectivity; CrystEngComm; Vol. 18, iss. 39
| Parent link: | CrystEngComm.— , 1999- Vol. 18, iss. 39.— 2016.— [С. 7614-7619] |
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| Samenvatting: | Title screen Lithium incorporation in metal–organic frameworks during solvothermal synthesis demonstrates a significant modification of the structure chemistry and surface properties of MOFs towards the adsorption selectivity of gas mixtures (CO2 and CH4) at ambient conditions. Variation of the lithium loading (xLi-MOF-5) led to tunability of the interpenetration resulting in materials with substantial differences in their properties. The behavior of xLi-MOF-5 was evaluated via phase identification based on XRD, functional group coordination using FTIR and adsorption measurements applying N2, CO2 and CH4 gas adsorption/desorption analysis. These efforts give rise to a new strategy to tailor MOFs for high efficiency CO2 adsorption and separation. Режим доступа: по договору с организацией-держателем ресурса |
| Taal: | Engels |
| Gepubliceerd in: |
2016
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| Online toegang: | http://dx.doi.org/10.1039/C6CE01522K |
| Formaat: | Elektronisch Hoofdstuk |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=652437 |