Control of interpenetration via in situ lithium incorporation in MOFs and their gas adsorption properties and selectivity
| Parent link: | CrystEngComm.— , 1999- Vol. 18, iss. 39.— 2016.— [С. 7614-7619] |
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| Main Author: | |
| Corporate Author: | |
| Other Authors: | , |
| Summary: | Title screen Lithium incorporation in metal–organic frameworks during solvothermal synthesis demonstrates a significant modification of the structure chemistry and surface properties of MOFs towards the adsorption selectivity of gas mixtures (CO2 and CH4) at ambient conditions. Variation of the lithium loading (xLi-MOF-5) led to tunability of the interpenetration resulting in materials with substantial differences in their properties. The behavior of xLi-MOF-5 was evaluated via phase identification based on XRD, functional group coordination using FTIR and adsorption measurements applying N2, CO2 and CH4 gas adsorption/desorption analysis. These efforts give rise to a new strategy to tailor MOFs for high efficiency CO2 adsorption and separation. Режим доступа: по договору с организацией-держателем ресурса |
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2016
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1039/C6CE01522K |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=652437 |
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| 200 | 1 | |a Control of interpenetration via in situ lithium incorporation in MOFs and their gas adsorption properties and selectivity |f S. Chaemchuem, Z. Kui, F. V. K. Verpoort | |
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| 320 | |a [References: p. 7618-7619 (32 tit.)] | ||
| 330 | |a Lithium incorporation in metal–organic frameworks during solvothermal synthesis demonstrates a significant modification of the structure chemistry and surface properties of MOFs towards the adsorption selectivity of gas mixtures (CO2 and CH4) at ambient conditions. Variation of the lithium loading (xLi-MOF-5) led to tunability of the interpenetration resulting in materials with substantial differences in their properties. The behavior of xLi-MOF-5 was evaluated via phase identification based on XRD, functional group coordination using FTIR and adsorption measurements applying N2, CO2 and CH4 gas adsorption/desorption analysis. These efforts give rise to a new strategy to tailor MOFs for high efficiency CO2 adsorption and separation. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t CrystEngComm |d 1999- | ||
| 463 | |t Vol. 18, iss. 39 |v [С. 7614-7619] |d 2016 | ||
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