Superficial Acid-Base Properties of Polymer Fibres; AIP Conference Proceedings; Vol. 1772 : Prospects of Fundamental Sciences Development (PFSD-2016)

Detalhes bibliográficos
Parent link:AIP Conference Proceedings
Vol. 1772 : Prospects of Fundamental Sciences Development (PFSD-2016).— 2016.— [020004, 8 p.]
Autor Corporativo: Национальный исследовательский Томский политехнический университет (ТПУ) Институт физики высоких технологий (ИФВТ) Кафедра сильноточной электроники (СЭ)
Outros Autores: Lysak I. A. Ilya Aleksandrovich, Skvortsova L. Lidia, Lysak G. Galina, Malinovskaya T. Tatiana, Sherstoboeva M. Maria
Resumo:Title screen
Protolytic properties of fine fibre plastics based on polypropylene, polyethyleneterephthalate and polycarbonate were investigated. Acidic (carboxylic, hydroxyl) and basic Lewis sites (esters, carbonates, epoxies) were discovered on fibres surface using IR spectroscopy. The number of active groups of various nature and their pKa values were evaluated by potentiometric titration in aqueous and non-aqueous media. The tested fibres possess a low capacity for both acidic and basic sites on it. The results indicate that all the polymer fibre materials (PFM) due to the presence of carboxyl groups on the surfaces, enable modification of their surfaces with metal nanoparticles, thereby giving them unique properties, e.g., photocatalytic and bactericidal.
Режим доступа: по договору с организацией-держателем ресурса
Idioma:inglês
Publicado em: 2016
Colecção:Synthesis and physicochemical characteristics of materials
Assuntos:
Acesso em linha:http://dx.doi.org/10.1063/1.4964526
http://earchive.tpu.ru/handle/11683/35013
Formato: Recurso Electrónico Capítulo de Livro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=652071

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330 |a Protolytic properties of fine fibre plastics based on polypropylene, polyethyleneterephthalate and polycarbonate were investigated. Acidic (carboxylic, hydroxyl) and basic Lewis sites (esters, carbonates, epoxies) were discovered on fibres surface using IR spectroscopy. The number of active groups of various nature and their pKa values were evaluated by potentiometric titration in aqueous and non-aqueous media. The tested fibres possess a low capacity for both acidic and basic sites on it. The results indicate that all the polymer fibre materials (PFM) due to the presence of carboxyl groups on the surfaces, enable modification of their surfaces with metal nanoparticles, thereby giving them unique properties, e.g., photocatalytic and bactericidal. 
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