Br2F7− and Br3F10−: peculiar anions showing μ2- and μ3-bridging F-atoms; Chemical Communications; Vol. 52, iss. 81

Br2F7− and Br3F10−: peculiar anions showing μ2- and μ3-bridging F-atoms; Chemical Communications; Vol. 52, iss. 81

Bibliographic Details
Parent link:Chemical Communications.— , 1989-
Vol. 52, iss. 81.— 2016.— [P. 12040-12043]
Corporate Author: Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра технологии органических веществ и полимерных материалов
Other Authors: Ivlev S. I. Sergey Ivanovich, Karttunen A. J. Antti, Ostvald R. V. Roman Vyacheslavovich, Kraus K. Kraus
Summary:Title screen
RbCl and CsCl react with BrF3 yielding the corresponding decafluoridotribromates(III), MBr3F10(M = Rb, Cs), which were structurally characterized for the first time. The Br3F10− anion is surprisingly not linear but contains a μ3-bridging fluorine atom and seems to be the first example of μ3-F bridging of Br atoms. The compounds are highly reactive and cannot be handled in glassware. As for the tetrafluoridobromates themselves, they are powerful oxidizers and thus suitable for the dry-chemical recycling of precious metals and additionally feature a significantly higher BrF3 content.
Language:English
Published: 2016
Subjects:
электронный ресурс
труды учёных ТПУ
Online Access:http://dx.doi.org/10.1039/C6CC06761A
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=651806

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