Modeling of Transalkylation Stage of Ethylbenzene Manufacturing with Zeolite-catalysts

Detaylı Bibliyografya
Parent link:Procedia Engineering
Vol. 152 : Oil and Gas Engineering (OGE-2016), Omsk, 25-30 April 2016 (Supported by PJSC Gazprom Neft).— 2016.— [P. 45-50]
Müşterek Yazar: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра химической технологии топлива и химической кибернетики (ХТТ)
Diğer Yazarlar: Koshkin S. A. Stanislav Aleksandrovich, Ignatova L. S. Lyubov Sergeevna, Ivashkina E. N. Elena Nikolaevna, Dolganova I. O. Irena Olegovna
Özet:Title screen
The analysis of industrial transalkylation reactor revealed regularities of catalyst activity and stability changes during its operation at change of basic technological parameters. A result of experimental data analysis, a list of possible reactions of transalkylation stage of ethylbenzene manufacturing zeolite-catalyst technology was developed. Values of Gibbs energies for change targets and adverse reactions, which were calculated with use of quantum chemistry methods, confirmed their thermodynamic probability at process conditions. The calculation results formed the basis of transalkylation process reaction network, needed to develop a mathematical model of ethylbenzene manufacturing zeolite-catalyst industrial technology.
Baskı/Yayın Bilgisi: 2016
Konular:
Online Erişim:http://dx.doi.org/10.1016/j.proeng.2016.07.622
Materyal Türü: Elektronik Kitap Bölümü
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=651758
Diğer Bilgiler
Özet:Title screen
The analysis of industrial transalkylation reactor revealed regularities of catalyst activity and stability changes during its operation at change of basic technological parameters. A result of experimental data analysis, a list of possible reactions of transalkylation stage of ethylbenzene manufacturing zeolite-catalyst technology was developed. Values of Gibbs energies for change targets and adverse reactions, which were calculated with use of quantum chemistry methods, confirmed their thermodynamic probability at process conditions. The calculation results formed the basis of transalkylation process reaction network, needed to develop a mathematical model of ethylbenzene manufacturing zeolite-catalyst industrial technology.
DOI:10.1016/j.proeng.2016.07.622