The promoting effect of pyridine ligands in the Pd-catalysed Heck–Matsuda reaction; New Journal of Chemistry; Vol. 40, iss. 10

Detalles Bibliográficos
Parent link:New Journal of Chemistry
Vol. 40, iss. 10.— 2016.— [P. 8855-8862]
Autor Corporativo: Национальный исследовательский Томский политехнический университет Институт физики высоких технологий Кафедра биотехнологии и органической химии
Outros autores: Khodja W. Walid, Leclair A. Alexandre, Rull-Barrull J. Jordi, Zammattio F. Francoise, Kutonova K. V. Ksenia Valentinovna, Trusova M. E. Marina Evgenievna, Felpin F.-Х. Francois-Xavier, Rodriguez Z. M. Zubiri Mireia
Summary:Title screen
An efficient Pd-catalyzed arylation reaction of challenging acyclic olefins, in the presence of an organic ligand, has been disclosed. Commercially available cheap pyridine-based ligands are able to promote good to excellent yields for poorly efficient Heck–Matsuda arylation reactions of several allylic alcohols. A wide range of electronically different arenediazonium salts bearing either electron-releasing or withdrawing groups have been used allowing the synthesis of a range of Я-aryl-methoxy-lactols. The catalytic system has been optimised, along with the reaction conditions, in order to achieve remarkable yields in less than 1 h.
Режим доступа: по договору с организацией-держателем ресурса
Idioma:inglés
Publicado: 2016
Subjects:
Acceso en liña:http://dx.doi.org/10.1039/C6NJ01717G
Formato: Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650629

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200 1 |a The promoting effect of pyridine ligands in the Pd-catalysed Heck–Matsuda reaction  |f W. Khodja [et al.] 
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300 |a Title screen 
320 |a [References: 48 tit.] 
330 |a An efficient Pd-catalyzed arylation reaction of challenging acyclic olefins, in the presence of an organic ligand, has been disclosed. Commercially available cheap pyridine-based ligands are able to promote good to excellent yields for poorly efficient Heck–Matsuda arylation reactions of several allylic alcohols. A wide range of electronically different arenediazonium salts bearing either electron-releasing or withdrawing groups have been used allowing the synthesis of a range of Я-aryl-methoxy-lactols. The catalytic system has been optimised, along with the reaction conditions, in order to achieve remarkable yields in less than 1 h. 
333 |a Режим доступа: по договору с организацией-держателем ресурса 
461 |t New Journal of Chemistry 
463 |t Vol. 40, iss. 10  |v [P. 8855-8862]  |d 2016 
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701 1 |a Leclair  |b A.  |g Alexandre 
701 1 |a Rull-Barrull  |b J.  |g Jordi 
701 1 |a Zammattio  |b F.  |g Francoise 
701 1 |a Kutonova  |b K. V.  |c chemist  |c Engineer of Tomsk Polytechnic University  |f 1990-  |g Ksenia Valentinovna  |3 (RuTPU)RU\TPU\pers\31822  |9 15917 
701 1 |a Trusova  |b M. E.  |c organic chemist  |c Associate professor of Tomsk Polytechnic University, Candidate of chemical sciences  |f 1982-  |g Marina Evgenievna  |3 (RuTPU)RU\TPU\pers\31823  |9 15918 
701 1 |a Felpin  |b F.-Х.  |g Francois-Xavier 
701 1 |a Rodriguez  |b Z. M.  |g Zubiri Mireia 
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