Exothermic characteristics of aluminum based nanomaterials

Bibliographic Details
Parent link:Powder Technology
Vol. 282.— 2015.— [P. 19–24]
Corporate Author: Национальный исследовательский Томский политехнический университет Институт физики высоких технологий Кафедра физики высоких технологий в машиностроении
Other Authors: Noor F. Fahad, Vorozhtsov A. B. Aleksandr Borisovich, Lerner M. I. Marat Izrailyevich, Wen D. Dongsheng
Summary:Title screen
Nano-structured energetic materials have been recently proposed as novel energy storage media where the exothermic reaction is the key to control the heat release process. The properties of nano-alloys, which can be engineered not only by the particle size, but also by varying their elemental compositions, are very appealing. This work conducted a comparative experimental study of the exothermic characteristics of two nanomaterials in the air, aluminum nanoparticles (nano-Al) and aluminum-copper nanoalloys (nano-AlCu) based on TGA/DSC studies. The results showed that the general exothermic characteristics of nano-AlCu were very similar to that of nano-Al but the nanoalloy was more reactive. The nano-AlCu was oxidized and ignited at lower temperature, and influenced by the heating rate. An early ignition was found for both nanomaterials, and the eutectic melting of the nano-alloy was believed to be mainly responsible for its early ignition.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2015
Subjects:
Online Access:http://dx.doi.org/10.1016/j.powtec.2014.12.058
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650435

MARC

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330 |a Nano-structured energetic materials have been recently proposed as novel energy storage media where the exothermic reaction is the key to control the heat release process. The properties of nano-alloys, which can be engineered not only by the particle size, but also by varying their elemental compositions, are very appealing. This work conducted a comparative experimental study of the exothermic characteristics of two nanomaterials in the air, aluminum nanoparticles (nano-Al) and aluminum-copper nanoalloys (nano-AlCu) based on TGA/DSC studies. The results showed that the general exothermic characteristics of nano-AlCu were very similar to that of nano-Al but the nanoalloy was more reactive. The nano-AlCu was oxidized and ignited at lower temperature, and influenced by the heating rate. An early ignition was found for both nanomaterials, and the eutectic melting of the nano-alloy was believed to be mainly responsible for its early ignition. 
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