General and Simple Method for the Synthesis of 3-nitroformazan Using Arenediazonium Tosylates; Current Organic Synthesis; Vol. 13, iss. 4
| Parent link: | Current Organic Synthesis.— , 2004- Vol. 13, iss. 4.— 2016.— [P. 623-628] |
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| Corporate Authors: | , |
| Other Authors: | , , , , , |
| Summary: | Title screen A general and simple procedure for the synthesis of 3-nitroformazan using arenediazonium tosylates was developed. This convenient procedure can be applied for the preparation of 3-nitroformazans containing electron-donating or electron-withdrawing groups. First the anomaly 1,5-bis(4-methoxyphenyl)-3-nitroformazan was synthesized as the mixture of TSSC (trans-syn, s-cis) and previously unknown for 3-nitroformazans TASC (transanti, s-cis) isomers. The structure and spectral characteristics of TASC isomer were explained using quantumchemical calculation with TDDFT/B3LYP/6-31++G(d,p) level of theory. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2016
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.2174/1570179413666160205002843 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650376 |
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| 200 | 1 | |a General and Simple Method for the Synthesis of 3-nitroformazan Using Arenediazonium Tosylates |f P. V. Petunin [et al.] | |
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| 300 | |a Title screen | ||
| 330 | |a A general and simple procedure for the synthesis of 3-nitroformazan using arenediazonium tosylates was developed. This convenient procedure can be applied for the preparation of 3-nitroformazans containing electron-donating or electron-withdrawing groups. First the anomaly 1,5-bis(4-methoxyphenyl)-3-nitroformazan was synthesized as the mixture of TSSC (trans-syn, s-cis) and previously unknown for 3-nitroformazans TASC (transanti, s-cis) isomers. The structure and spectral characteristics of TASC isomer were explained using quantumchemical calculation with TDDFT/B3LYP/6-31++G(d,p) level of theory. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Current Organic Synthesis |d 2004- | ||
| 463 | |t Vol. 13, iss. 4 |v [P. 623-628] |d 2016 | ||
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