High resolution analysis of C2D4 in the region of 600–1150 cm-1
| Parent link: | Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 182.— 2016.— [P. 55-70] |
|---|---|
| Autor corporatiu: | |
| Altres autors: | , , , , , , , |
| Sumari: | Title screen High-accurate Fourier-transform infrared spectra of C2D4 were recorded and analyzed in the region of 600-1150 cm−1 where the bands ν7(B1u), ν10(B2u), ν12(B3u) are located as well as the ν4(Au) band which is forbidden by the symmetry of the molecule. The ground state rotational structure was re-analyzed by the use of ground state combination differences obtained on the basis of infrared transitions of the ν12 and ν7absorption bands. This gave us the possibility to considerably improve the rotational and centrifugal parameters of the ground vibrational state. The analysis of the experimental data and the subsequent weighted-fit procedure of the Hamiltonian parameters allowed us to reproduce the initial 4405 “experimental” ro-vibrational energy values with the. Режим доступа: по договору с организацией-держателем ресурса |
| Idioma: | anglès |
| Publicat: |
2016
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| Matèries: | |
| Accés en línia: | http://dx.doi.org/10.1016/j.jqsrt.2016.04.026 |
| Format: | Electrònic Capítol de llibre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650147 |
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| 200 | 1 | |a High resolution analysis of C2D4 in the region of 600–1150 cm-1 |f O. N. Ulenikov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 72 tit.] | ||
| 330 | |a High-accurate Fourier-transform infrared spectra of C2D4 were recorded and analyzed in the region of 600-1150 cm−1 where the bands ν7(B1u), ν10(B2u), ν12(B3u) are located as well as the ν4(Au) band which is forbidden by the symmetry of the molecule. The ground state rotational structure was re-analyzed by the use of ground state combination differences obtained on the basis of infrared transitions of the ν12 and ν7absorption bands. This gave us the possibility to considerably improve the rotational and centrifugal parameters of the ground vibrational state. The analysis of the experimental data and the subsequent weighted-fit procedure of the Hamiltonian parameters allowed us to reproduce the initial 4405 “experimental” ro-vibrational energy values with the. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Quantitative Spectroscopy and Radiative Transfer | ||
| 463 | |t Vol. 182 |v [P. 55-70] |d 2016 | ||
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| 610 | 1 | |a колебательные состояния | |
| 610 | 1 | |a спектры | |
| 610 | 1 | |a спектры высокого разрешения | |
| 610 | 1 | |a спектроскопические параметры | |
| 701 | 1 | |a Ulenekov (Ulenikov) |b O. N. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1949- |g Oleg Nikolaevich |3 (RuTPU)RU\TPU\pers\34331 |9 17837 | |
| 701 | 1 | |a Gromova |b O. V. |c physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1982- |g Olga Vasilievna |3 (RuTPU)RU\TPU\pers\34333 |9 17839 | |
| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |3 (RuTPU)RU\TPU\pers\34450 |9 17851 | |
| 701 | 1 | |a Fomchenko |b A. L. |c physicist |c research engineer at Tomsk Polytechnic University, candidate of physical and mathematical Sciences |f 1987- |g Anna Leonidovna |3 (RuTPU)RU\TPU\pers\34089 |9 17645 | |
| 701 | 0 | |a Zhang Fangce |c Chinese physicist |c technician of Tomsk Polytechnic University |f 1993- |3 (RuTPU)RU\TPU\pers\42500 |9 21546 | |
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| 701 | 1 | |a Maul |b C. | |
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