Transition metal-mediated oxidations utilizing monomeric iodosyl- and iodylarene species

Transition metal-mediated oxidations utilizing monomeric iodosyl- and iodylarene species

Podrobná bibliografie
Parent link:Tetrahedron: The International Journal for the Rapid Publication of Full Original Research Papers and Critical Reviews Organic Chemistry
Vol. 66, iss. 31.— 2010.— [P. 5745-5752]
Další autoři: Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Nemykin V. N., Zhdankin V. V. Viktor Vladimirovich
Shrnutí:Title screen
Several transition metal-mediated oxidations using hypervalent iodine species are reported. A convenient procedure for preparation of iodylarenes via RuCl3-catalyzed oxidation of iodoarenes has been developed. This procedure allows the generation of highly reactive monomeric iodine(V) species, which are excellent oxidants toward alcohols and hydrocarbons in situ. A broad range of substrates can be oxidized to carbonyl compounds by a tandem catalytic system based on the Ru(III)-catalyzed reoxidation of ArIO to ArIO2using Oxone® as oxidant. It was shown that electrophilic iodine(III) species, originating from oligomeric iodosylbenzene sulfate (PhIO)3SO3, are efficient oxygenating agents in catalytic oxidation of aromatic hydrocarbons in the presence of metalloporphyrin complexes.
Режим доступа: по договору с организацией-держателем ресурса
Jazyk:angličtina
Vydáno: 2010
Témata:
электронный ресурс
труды учёных ТПУ
окисление
ариолиодиды
соединения
йод
рутений
порфирины
катализаторы
On-line přístup:http://dx.doi.org/10.1016/j.tet.2010.04.046
Médium: Elektronický zdroj Kapitola
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650107

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