Transition metal-mediated oxidations utilizing monomeric iodosyl- and iodylarene species; Tetrahedron; Vol. 66, iss. 31
| Parent link: | Tetrahedron: The International Journal for the Rapid Publication of Full Original Research Papers and Critical Reviews Organic Chemistry Vol. 66, iss. 31.— 2010.— [P. 5745-5752] |
|---|---|
| Diğer Yazarlar: | , , |
| Özet: | Title screen Several transition metal-mediated oxidations using hypervalent iodine species are reported. A convenient procedure for preparation of iodylarenes via RuCl3-catalyzed oxidation of iodoarenes has been developed. This procedure allows the generation of highly reactive monomeric iodine(V) species, which are excellent oxidants toward alcohols and hydrocarbons in situ. A broad range of substrates can be oxidized to carbonyl compounds by a tandem catalytic system based on the Ru(III)-catalyzed reoxidation of ArIO to ArIO2using Oxone® as oxidant. It was shown that electrophilic iodine(III) species, originating from oligomeric iodosylbenzene sulfate (PhIO)3SO3, are efficient oxygenating agents in catalytic oxidation of aromatic hydrocarbons in the presence of metalloporphyrin complexes. Режим доступа: по договору с организацией-держателем ресурса |
| Dil: | İngilizce |
| Baskı/Yayın Bilgisi: |
2010
|
| Konular: | |
| Online Erişim: | http://dx.doi.org/10.1016/j.tet.2010.04.046 |
| Materyal Türü: | Elektronik Kitap Bölümü |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650107 |
MARC
| LEADER | 00000naa0a2200000 4500 | ||
|---|---|---|---|
| 001 | 650107 | ||
| 005 | 20250318153757.0 | ||
| 035 | |a (RuTPU)RU\TPU\network\15289 | ||
| 035 | |a RU\TPU\network\11001 | ||
| 090 | |a 650107 | ||
| 100 | |a 20160909d2010 k||y0rusy50 ba | ||
| 101 | 0 | |a eng | |
| 102 | |a US | ||
| 135 | |a drcn ---uucaa | ||
| 181 | 0 | |a i | |
| 182 | 0 | |a b | |
| 200 | 1 | |a Transition metal-mediated oxidations utilizing monomeric iodosyl- and iodylarene species |f M. S. Yusubov, V. N. Nemykin, V. V. Zhdankin | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 5752 (27 tit.)] | ||
| 330 | |a Several transition metal-mediated oxidations using hypervalent iodine species are reported. A convenient procedure for preparation of iodylarenes via RuCl3-catalyzed oxidation of iodoarenes has been developed. This procedure allows the generation of highly reactive monomeric iodine(V) species, which are excellent oxidants toward alcohols and hydrocarbons in situ. A broad range of substrates can be oxidized to carbonyl compounds by a tandem catalytic system based on the Ru(III)-catalyzed reoxidation of ArIO to ArIO2using Oxone® as oxidant. It was shown that electrophilic iodine(III) species, originating from oligomeric iodosylbenzene sulfate (PhIO)3SO3, are efficient oxygenating agents in catalytic oxidation of aromatic hydrocarbons in the presence of metalloporphyrin complexes. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Tetrahedron |o The International Journal for the Rapid Publication of Full Original Research Papers and Critical Reviews Organic Chemistry | ||
| 463 | |t Vol. 66, iss. 31 |v [P. 5745-5752] |d 2010 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a окисление | |
| 610 | 1 | |a ариолиодиды | |
| 610 | 1 | |a соединения | |
| 610 | 1 | |a йод | |
| 610 | 1 | |a рутений | |
| 610 | 1 | |a порфирины | |
| 610 | 1 | |a катализаторы | |
| 701 | 1 | |a Yusubov |b M. S. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1961- |g Mekhman Suleiman-Ogly (Suleimanovich) |3 (RuTPU)RU\TPU\pers\31833 |9 15928 | |
| 701 | 1 | |a Nemykin |b V. N. | |
| 701 | 1 | |a Zhdankin |b V. V. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1956- |g Viktor Vladimirovich |y Tomsk |3 (RuTPU)RU\TPU\pers\35758 |9 18915 | |
| 801 | 2 | |a RU |b 63413507 |c 20160909 |g RCR | |
| 856 | 4 | |u http://dx.doi.org/10.1016/j.tet.2010.04.046 | |
| 942 | |c CF | ||