Synthetic applications of pseudocyclic hypervalent iodine compounds; Organic and Biomolecular Chemistry; Vol. 14

Synthetic applications of pseudocyclic hypervalent iodine compounds; Organic and Biomolecular Chemistry; Vol. 14

Xehetasun bibliografikoak
Parent link:Organic and Biomolecular Chemistry
Vol. 14.— 2016.— [P. 4771-4781]
Egile nagusia: Yoshimura A. Akira
Erakunde egilea: Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра технологии органических веществ и полимерных материалов
Beste egile batzuk: Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Zhdankin V. V. Viktor Vladimirovich
Gaia:Title screen
Hypervalent iodine compounds have found wide practical application as versatile, efficient, and sustainable reagents for organic synthesis. Pseudocyclic hypervalent iodine derivatives are characterized by the presence of additional intramolecular non-covalent coordination at the iodine center, which leads to significant alteration of their physical and chemical properties. In comparison with common hypervalent iodine reagents, these pseudocyclic compounds have higher thermal stability, better solubility, and improved reactivity. In recent years, pseudocyclic hypervalent iodine reagents are increasingly used in organic synthesis as environmentally friendly selective oxidants and electrophiles. Furthermore, numerous enantioselective reactions mediated by chiral pseudocyclic hypervalent iodine species have been recently developed. In the present review, the preparation and structural features of pseudocyclic iodine(III) and iodine(V) derivatives are discussed, and recent developments in their synthetic applications are summarized.
Режим доступа: по договору с организацией-держателем ресурса
Hizkuntza:ingelesa
Argitaratua: 2016
Gaiak:
электронный ресурс
труды учёных ТПУ
йод
органический синтез
соединения
применение
структурные особенности
обзоры
Sarrera elektronikoa:https://doi.org/10.1039/C6OB00773B
Formatua: Baliabide elektronikoa Liburu kapitulua
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650094

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