Synthetic applications of pseudocyclic hypervalent iodine compounds; Organic and Biomolecular Chemistry; Vol. 14
| Источник: | Organic and Biomolecular Chemistry Vol. 14.— 2016.— [P. 4771-4781] |
|---|---|
| Главный автор: | |
| Автор-организация: | |
| Другие авторы: | , |
| Примечания: | Title screen Hypervalent iodine compounds have found wide practical application as versatile, efficient, and sustainable reagents for organic synthesis. Pseudocyclic hypervalent iodine derivatives are characterized by the presence of additional intramolecular non-covalent coordination at the iodine center, which leads to significant alteration of their physical and chemical properties. In comparison with common hypervalent iodine reagents, these pseudocyclic compounds have higher thermal stability, better solubility, and improved reactivity. In recent years, pseudocyclic hypervalent iodine reagents are increasingly used in organic synthesis as environmentally friendly selective oxidants and electrophiles. Furthermore, numerous enantioselective reactions mediated by chiral pseudocyclic hypervalent iodine species have been recently developed. In the present review, the preparation and structural features of pseudocyclic iodine(III) and iodine(V) derivatives are discussed, and recent developments in their synthetic applications are summarized. Режим доступа: по договору с организацией-держателем ресурса |
| Язык: | английский |
| Опубликовано: |
2016
|
| Предметы: | |
| Online-ссылка: | https://doi.org/10.1039/C6OB00773B |
| Формат: | Электронный ресурс Статья |
| Запись в KOHA: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=650094 |
MARC
| LEADER | 00000naa0a2200000 4500 | ||
|---|---|---|---|
| 001 | 650094 | ||
| 005 | 20250318153757.0 | ||
| 035 | |a (RuTPU)RU\TPU\network\15276 | ||
| 035 | |a RU\TPU\network\8197 | ||
| 090 | |a 650094 | ||
| 100 | |a 20160908d2016 k||y0rusy50 ba | ||
| 101 | 0 | |a eng | |
| 102 | |a GB | ||
| 135 | |a drcn ---uucaa | ||
| 181 | 0 | |a i | |
| 182 | 0 | |a b | |
| 200 | 1 | |a Synthetic applications of pseudocyclic hypervalent iodine compounds |f А. Yoshimura, M. S. Yusubov, V. V. Zhdankin | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 4780-4781 (99 tit.)] | ||
| 330 | |a Hypervalent iodine compounds have found wide practical application as versatile, efficient, and sustainable reagents for organic synthesis. Pseudocyclic hypervalent iodine derivatives are characterized by the presence of additional intramolecular non-covalent coordination at the iodine center, which leads to significant alteration of their physical and chemical properties. In comparison with common hypervalent iodine reagents, these pseudocyclic compounds have higher thermal stability, better solubility, and improved reactivity. In recent years, pseudocyclic hypervalent iodine reagents are increasingly used in organic synthesis as environmentally friendly selective oxidants and electrophiles. Furthermore, numerous enantioselective reactions mediated by chiral pseudocyclic hypervalent iodine species have been recently developed. In the present review, the preparation and structural features of pseudocyclic iodine(III) and iodine(V) derivatives are discussed, and recent developments in their synthetic applications are summarized. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Organic and Biomolecular Chemistry | ||
| 463 | |t Vol. 14 |v [P. 4771-4781] |d 2016 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a йод | |
| 610 | 1 | |a органический синтез | |
| 610 | 1 | |a соединения | |
| 610 | 1 | |a применение | |
| 610 | 1 | |a структурные особенности | |
| 610 | 1 | |a обзоры | |
| 700 | 1 | |a Yoshimura |b A. |c chemical engineer |c Professor of Tomsk Polytechnic University |f 1981- |g Akira |3 (RuTPU)RU\TPU\pers\39852 |9 21126 | |
| 701 | 1 | |a Yusubov |b M. S. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1961- |g Mekhman Suleiman-Ogly (Suleimanovich) |3 (RuTPU)RU\TPU\pers\31833 |9 15928 | |
| 701 | 1 | |a Zhdankin |b V. V. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1956- |g Viktor Vladimirovich |y Tomsk |3 (RuTPU)RU\TPU\pers\35758 |9 18915 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Институт природных ресурсов |b Кафедра технологии органических веществ и полимерных материалов |3 (RuTPU)RU\TPU\col\18659 |9 27112 |
| 801 | 2 | |a RU |b 63413507 |c 20230329 |g RCR | |
| 856 | 4 | |u https://doi.org/10.1039/C6OB00773B | |
| 942 | |c CF | ||