Photoactive TiO2 coatings obtained by Plasma Electrolytic Oxidation in refrigerated electrolytes; Applied Surface Science; Vol. 385

التفاصيل البيبلوغرافية
Parent link:Applied Surface Science.— , 1985-
Vol. 385.— 2016.— [P. 498-505]
مؤلف مشترك: Национальный исследовательский Томский политехнический университет Физико-технический институт Кафедра экспериментальной физики
مؤلفون آخرون: Franz S. Silvia, Perego D. Daniele, Marchese M. Marchese, Lucotti A. Andrea, Bestetti M. Massimiliano
الملخص:Title screen
The effect of synthesis conditions on the properties of nanoporous TiO2 coatings obtained by PEO in refrigerated electrolytes have been investigated. Linear sweep voltammetry was carried out on the TiO2 coatings, in dark and under UV-C irradiation, in order to assess the photoelectrochemical behavior of samples. The largest photocurrents (0.18 mA/cm2) were measured on TiO2 coatings obtained by PEO in refrigerated aqueous solutions. UV-vis spectra revealed that lowering the processing temperature from 20 to −3.5 °C induced a blue-shift of the absorption band of the TiO2coatings from 3.05 to 3.42 eV. The main advantage of PEO in refrigerated aqueous solutions over current approaches, based on anodic oxidation and thermal treatments, is that the synthesis of photoactive TiO2 coatings can be carried out in a relatively easy, quick and reproducible way, without annealing pre- and post-treatments. Furthermore, by controlling the solution temperature in PEO process, the photocurrent of the resulting TiO2 coating reaches quite high values.
AM_Agreement
اللغة:الإنجليزية
منشور في: 2016
الموضوعات:
الوصول للمادة أونلاين:http://dx.doi.org/10.1016/j.apsusc.2016.05.032
التنسيق: الكتروني فصل الكتاب
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=649819

MARC

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330 |a The effect of synthesis conditions on the properties of nanoporous TiO2 coatings obtained by PEO in refrigerated electrolytes have been investigated. Linear sweep voltammetry was carried out on the TiO2 coatings, in dark and under UV-C irradiation, in order to assess the photoelectrochemical behavior of samples. The largest photocurrents (0.18 mA/cm2) were measured on TiO2 coatings obtained by PEO in refrigerated aqueous solutions. UV-vis spectra revealed that lowering the processing temperature from 20 to −3.5 °C induced a blue-shift of the absorption band of the TiO2coatings from 3.05 to 3.42 eV. The main advantage of PEO in refrigerated aqueous solutions over current approaches, based on anodic oxidation and thermal treatments, is that the synthesis of photoactive TiO2 coatings can be carried out in a relatively easy, quick and reproducible way, without annealing pre- and post-treatments. Furthermore, by controlling the solution temperature in PEO process, the photocurrent of the resulting TiO2 coating reaches quite high values. 
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