Clay mineralogy and unconventional hydrocarbon shale reservoirs in the USA. II. Implications of predominantly illitic clays on the physico-chemical properties of shales

Clay mineralogy and unconventional hydrocarbon shale reservoirs in the USA. II. Implications of predominantly illitic clays on the physico-chemical properties of shales

Détails bibliographiques
Parent link:Earth-Science Reviews: scientific journal
Vol. 158.— 2016.— [8 p.]
Auteur principal: Wilson M. J. Michael Jeffrey
Collectivités auteurs: Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра общей геологии и землеустройства, Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра проектирования объектов нефтегазового комплекса
Autres auteurs: Wilson L., Shaldybin M. V. Mikhail Viktorovich
Résumé:Title screen
Re-interpretation of R3 mixed-layer illite-smectite (I/S) as consisting only of thin (< 50 Å) illite leads to the question of whether this really matters in the context of the overall physico-chemical properties of the shales in which this clay material is found, such as in the unconventional hydrocarbon shale reservoirs of the USA. It is argued here that the distinction between regarding the clay mineralogy of these shales as partly smectitic or wholly illitic is important, particularly when one considers the interactions between charged clay surfaces and aqueous pore fluids. These interactions are broadly discussed within the framework of the double electric layer (DEL) theory which successfully accounts for a range of phenomena that are observed in colloidal sols of clay minerals dispersed in aqueous solutions of varied chemical composition. Particle interactions in these sols depend to a large extent on the thickness of the DEL. In general, this thickness is controlled by the balance between the external surface charge density of the clay particle and the electrolyte concentration of the aqueous solution, because the higher the surface charge density the thicker will be the DEL, and the more concentrated the aqueous solution the thinner will be the DEL. Although shales are not colloids, in situations where the pore size is similar to that of the thickness of the DEL the same principles that govern particle-fluid interactions in the colloidal state should still apply.
Режим доступа: по договору с организацией-держателем ресурса
Publié: 2016
Sujets:
электронный ресурс
труды учёных ТПУ
Accès en ligne:http://dx.doi.org/10.1016/j.earscirev.2016.04.005
Format: Électronique Chapitre de livre
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=649459

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