Structural self-organization of solid-state products during interaction of halogenated compounds with bulk Ni-Cr alloy

Structural self-organization of solid-state products during interaction of halogenated compounds with bulk Ni-Cr alloy

Bibliographic Details
Parent link:Materials Letters
Vol. 179.— 2016.— [P. 30–33]
Corporate Authors: Национальный исследовательский Томский политехнический университет Энергетический институт Кафедра атомных и тепловых электростанций, Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра физической и аналитической химии
Other Authors: Kenzhin R. M., Bauman Yu. I., Volodin A. M., Mishakov I. V. Iljya Vladimirovich, Vedyagin A. A. Aleksey Anatolievich
Summary:Title screen
In this work, the approach of Reactions under Autogenic Pressure at Elevated Temperature (RAPET) was applied to study the decomposition of different halogen-containing organic compounds over bulk Ni-Cr alloy (nichrome wire). Method of ferromagnetic resonance (FMR) was shown to be rather informative for in situ studying of catalytic corrosion processes taking place on the surface of the alloy during interaction with halogenated hydrocarbons which is accompanied by the formation of nickel nanoparticles. Highly organized submicron structures of halogenated Ni-species was found to appear at the RAPET conditions when the closed reaction volume contains both hydrogen and halogen sources. Such species were shown to be stable in a narrow range of temperature. The obtained metastable intermediates were characterized by scanning electron microscopy (SEM).
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2016
Subjects:
электронный ресурс
труды учёных ТПУ
полупроводниковые изделия
структурная самоорганизация
галоидирование
сплавы
Online Access:http://dx.doi.org/10.1016/j.matlet.2016.05.039
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=649355

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