Structural self-organization of solid-state products during interaction of halogenated compounds with bulk Ni-Cr alloy; Materials Letters; Vol. 179

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Parent link:Materials Letters
Vol. 179.— 2016.— [P. 30–33]
Korporace: Национальный исследовательский Томский политехнический университет Энергетический институт Кафедра атомных и тепловых электростанций, Национальный исследовательский Томский политехнический университет Институт природных ресурсов Кафедра физической и аналитической химии
Další autoři: Kenzhin R. M., Bauman Yu. I., Volodin A. M., Mishakov I. V. Iljya Vladimirovich, Vedyagin A. A. Aleksey Anatolievich
Shrnutí:Title screen
In this work, the approach of Reactions under Autogenic Pressure at Elevated Temperature (RAPET) was applied to study the decomposition of different halogen-containing organic compounds over bulk Ni-Cr alloy (nichrome wire). Method of ferromagnetic resonance (FMR) was shown to be rather informative for in situ studying of catalytic corrosion processes taking place on the surface of the alloy during interaction with halogenated hydrocarbons which is accompanied by the formation of nickel nanoparticles. Highly organized submicron structures of halogenated Ni-species was found to appear at the RAPET conditions when the closed reaction volume contains both hydrogen and halogen sources. Such species were shown to be stable in a narrow range of temperature. The obtained metastable intermediates were characterized by scanning electron microscopy (SEM).
Режим доступа: по договору с организацией-держателем ресурса
Jazyk:angličtina
Vydáno: 2016
Témata:
On-line přístup:http://dx.doi.org/10.1016/j.matlet.2016.05.039
Médium: Elektronický zdroj Kapitola
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=649355

MARC

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200 1 |a Structural self-organization of solid-state products during interaction of halogenated compounds with bulk Ni-Cr alloy  |f R. M. Kenzhin [at al.] 
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320 |a [References: p. 33 (23 tit.)] 
330 |a In this work, the approach of Reactions under Autogenic Pressure at Elevated Temperature (RAPET) was applied to study the decomposition of different halogen-containing organic compounds over bulk Ni-Cr alloy (nichrome wire). Method of ferromagnetic resonance (FMR) was shown to be rather informative for in situ studying of catalytic corrosion processes taking place on the surface of the alloy during interaction with halogenated hydrocarbons which is accompanied by the formation of nickel nanoparticles. Highly organized submicron structures of halogenated Ni-species was found to appear at the RAPET conditions when the closed reaction volume contains both hydrogen and halogen sources. Such species were shown to be stable in a narrow range of temperature. The obtained metastable intermediates were characterized by scanning electron microscopy (SEM). 
333 |a Режим доступа: по договору с организацией-держателем ресурса 
461 |t Materials Letters 
463 |t Vol. 179  |v [P. 30–33]  |d 2016 
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