Tuning metal sites of DABCO MOF for gas purification at ambient conditions
| Parent link: | Microporous and Mesoporous Materials Vol. 201.— 2015.— [P. 277–285] |
|---|---|
| Corporate Author: | |
| Other Authors: | , , , , , , |
| Summary: | Title screen Metal–organic frameworks (MOFs) have emerged as new porous materials for capture and separation of binary gas mixtures. Tuning the metal sites in MOF structures has an impact on properties, which enhance affinity of gas adsorption and selectivity (e.g., surface area, cavity, electric field, etc.). The synthesis and characterization of a M-DABCO series (M = Ni, Co, Cu, Zn) of MOFs are described in this study. The experiments were conducted using multicomponent gas mixtures and the Ideal Adsorbed Solution Theory (IAST) was applied to determine the CO2/CH4 selectivity. Experimental adsorption isotherms were fitted with a model equation to evaluate the characteristic adsorption energy (Isosteric, Qst) of this series. The Ni metal in the M-DABCO series reveals the best performance concerning CO2 adsorption and CH4/CO2 selectivity at ambient conditions based on IAST calculations. The combination of characterizations, calculations and adsorption experiments were used to discuss the metal impact on the adsorption sites in the M-DABCO series at ambient conditions. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2015
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1016/j.micromeso.2014.09.038 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=649115 |
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| 200 | 1 | |a Tuning metal sites of DABCO MOF for gas purification at ambient conditions |f Chaemchuen Somboon, K. Zhou, N. A. Kabir [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 284-285 (68 tit.)] | ||
| 330 | |a Metal–organic frameworks (MOFs) have emerged as new porous materials for capture and separation of binary gas mixtures. Tuning the metal sites in MOF structures has an impact on properties, which enhance affinity of gas adsorption and selectivity (e.g., surface area, cavity, electric field, etc.). The synthesis and characterization of a M-DABCO series (M = Ni, Co, Cu, Zn) of MOFs are described in this study. The experiments were conducted using multicomponent gas mixtures and the Ideal Adsorbed Solution Theory (IAST) was applied to determine the CO2/CH4 selectivity. Experimental adsorption isotherms were fitted with a model equation to evaluate the characteristic adsorption energy (Isosteric, Qst) of this series. The Ni metal in the M-DABCO series reveals the best performance concerning CO2 adsorption and CH4/CO2 selectivity at ambient conditions based on IAST calculations. The combination of characterizations, calculations and adsorption experiments were used to discuss the metal impact on the adsorption sites in the M-DABCO series at ambient conditions. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Microporous and Mesoporous Materials | ||
| 463 | |t Vol. 201 |v [P. 277–285] |d 2015 | ||
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| 610 | 1 | |a электронный ресурс | |
| 701 | 0 | |a Chaemchuen Somboon |c chemist-technologist |c researcher at Tomsk Polytechnic University, Ph.D |f 1984- |3 (RuTPU)RU\TPU\pers\42620 |9 21555 | |
| 701 | 1 | |a Zhou |b K. |g Kui | |
| 701 | 1 | |a Kabir |b N. A. |g Nawsad Alam | |
| 701 | 1 | |a Chen |b Y. |g Yao | |
| 701 | 1 | |a Ke |b X. |g Xiaoxing | |
| 701 | 1 | |a VanTendeloo |b G. |g Gustaaf | |
| 701 | 1 | |a Verpoort |b F. V. K. |c Chemical Engineer |c Professor of Tomsk Polytechnic University, doctor of chemical Sciences |f 1963- |g Frensis Valter Kornelius |3 (RuTPU)RU\TPU\pers\35059 |9 18334 | |
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