Compounds of Group 14 Elements with an Element–Element (E = Si, Ge, Sn) Bond: Effect of the Nature of the Element Atom; Organometallics; Vol. 34, iss. 12

Compounds of Group 14 Elements with an Element–Element (E = Si, Ge, Sn) Bond: Effect of the Nature of the Element Atom; Organometallics; Vol. 34, iss. 12

Bibliographic Details
Parent link:Organometallics
Vol. 34, iss. 12.— 2015.— [P. 2765–2774]
Corporate Author: Национальный исследовательский Томский политехнический университет Юргинский технологический институт (филиал) Кафедра естественного научного образования
Other Authors: Zaitsev K. V. Kirill, Lermontova E. Kh. Elmira, Churakov A. V. Churakov, Tafeenko V. A. Viktor, Tarasevich B. N. Boris, Poleshchuk O. Kh. Oleg Khemovich, Kharcheva A. V. Anastasia, Magdesieva T. V. Tatiana, Nikitin O. M. Oleg, Zaitseva G. S. Galina, Sergey S. S. Sergey
Summary:Title screen
Two series of germanium compounds, (p-Tol)3Ge-MMe3 (M = Si (1), Ge (2), Sn (3)) and (Me3Si)3Ge-MPh3 (M = Ge (4), Sn (5)), were prepared using lithium or potassium intermediates. The changing of the reaction conditions results in trigermane Ph3Ge-Ge(SiMe3)2-GePh3 (6). The molecular structures of 1, 2, and 6 were investigated by X-ray analysis. By UV/visible spectroscopy it is established that introduction of a tin atom results in a significant bathochromic absorption shift. Furthermore, according to cyclic voltammetry, oxidation potentials decrease in the order 1 > 2 > 3. The electronic structures of 1-4 and related (Me3Si)3Ge-SiPh3 were investigated by DFT calculations. Fluorescence properties of 1-3 were studied in the solid state and in solution; for compound 3 phosphorescence (lifetime is 4.58 ms) is observed in the solid state.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2015
Subjects:
электронный ресурс
труды учёных ТПУ
Online Access:http://dx.doi.org/10.1021/om501293t
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=648763

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