Ligand Constraints and Synthesis of Metal–Organic Polyhedra

Ligand Constraints and Synthesis of Metal–Organic Polyhedra

Bibliographic Details
Parent link:Australian Journal of Chemistry: International journal for chemical science.— , 1948-
Vol. 68, iss. 5.— 2015.— [P. 707-730]
Main Author: Vardhan H. Harsh
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Other Authors: Verpoort F. V. K. Frensis Valter Kornelius
Summary:Title screen
Metal–organic polyhedra are three dimensional discrete structures typically constructed by the self-assembly of metal ions and ligands. The synthesis and geometry of discrete structures entirely rely on the choice of metal ions, ligand constraints such as steric bulk, bend angle, and functionalities, and the nature of applied solvents. As a result, they provide tailorable internal volume and usually hydrophobic nature to the cavity that in turn makes them one of the prominent host molecules for a range of applications. This review highlights the intervention of ligand constraints, precisely bend angle (0°, 60°, 120°, and 180°), hydroxyl functionalities, and the role of concepts such as molecular panelling and subcomponent self-assembly in the synthesis of polyhedra.
Published: 2015
Subjects:
электронный ресурс
труды учёных ТПУ
Online Access:http://dx.doi.org/10.1071/CH14484
Format: Electronic Book
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=648256

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