Analysis of The High-Resolution Fourier Spectrum of The v6 Band of The Cis-C2H2D2 Molecule; Russian Physics Journal; Vol. 58, iss. 11

Analysis of The High-Resolution Fourier Spectrum of The v6 Band of The Cis-C2H2D2 Molecule; Russian Physics Journal; Vol. 58, iss. 11

Chi tiết về thư mục
Parent link:	Russian Physics Journal: Scientific Journal.— , 1965- Vol. 58, iss. 11.— 2016.— [P. 1587-1591]
Tác giả của công ty:	Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра общей физики (ОФ)
Tác giả khác:	Konov I. A., Chertavskikh Yu. V. Yulia Vladimirovna, Fomchenko A. L. Anna Leonidovna, Aslapovskaya Yu. S. Yuliya Sergeevna, Zhdanovich S. A., Sydow C.
Tóm tắt:	Title screen The spectrum of the ν6 band of the cis-ethylene-d2 molecule (cis-C2H2D2) is recorded with a Bruker IFS 125 HR Fourier spectrometer in the range 580-1210 cm-1 with resolution of 0.0021 cm-1. An analysis of the experimental spectrum allows more than 1500 transitions belonging to this band to be assigned that by more than 2.5 times greater than it has been known in the literature so far. The obtained experimental data are then used to determine the model parameters of the molecule (the effective Hamiltonian in the A-reduction and I′- representation). Strong resonance interaction with the band ν4 forbidden in absorption by the symmetry of a molecule is taken into account. 10 parameters of the Hamiltonian obtained by solving inverse spectroscopic problem reproduce 427 initial experimental energies (more than 1500 transitions) with accuracy close to the experimental uncertainty. Режим доступа: по договору с организацией-держателем ресурса
Ngôn ngữ:	Tiếng Anh
Được phát hành:	2016
Những chủ đề:	электронный ресурс труды учёных ТПУ вращение молекулы параметры
Truy cập trực tuyến:	http://dx.doi.org/10.1007/s11182-016-0687-x
Định dạng:	Điện tử Chương của sách
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=647791

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