Halogenating and nitrating activity of reagents based on sodium nitrate and alkali metal halides in acetic acid; Russian Journal of Organic Chemistry; Vol. 40, iss. 7

Halogenating and nitrating activity of reagents based on sodium nitrate and alkali metal halides in acetic acid; Russian Journal of Organic Chemistry; Vol. 40, iss. 7

Xehetasun bibliografikoak
Parent link:	Russian Journal of Organic Chemistry.— , 2001- Vol. 40, iss. 7.— 2004.— [P. 917-923]
Beste egile batzuk:	Filimonov V. D. Viktor Dmitrievich, Kulmanakova Yu. Yu., Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Perederina I. A., Ki-Whan Chi, Poleshchuk O. Kh. Oleg Khemovich
Gaia:	Title screen Alkali metal halides NaF, KCl, and KBr sharply enhance the nitrating activity of sodium nitrate in acetic acid with respect to 9-methylcarbazole. In the presence of KI and KBr, both nitration and halogenation of the substrate occurs, while KCl and NaF promote only the nitration process. The results may be interpreted in terms of formation of the corresponding nitryl halides XNO2 (X = F, Cl, Br, I) whose structure and reactivity were examined in the framework of the density functional theory (DFT B3LYP/3-21G*). Режим доступа: по договору с организацией-держателем ресурса
Hizkuntza:	ingelesa
Argitaratua:	2004
Gaiak:	электронный ресурс труды учёных ТПУ reagents acetic acid alkali metals реагенты щелочные металлы уксусная кислота
Sarrera elektronikoa:	http://dx.doi.org/10.1023/B:RUJO.0000045178.33131.c2
Formatua:	Baliabide elektronikoa Liburu kapitulua
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=647610

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