Halogenating and nitrating activity of reagents based on sodium nitrate and alkali metal halides in acetic acid
| Parent link: | Russian Journal of Organic Chemistry.— , 2001- Vol. 40, iss. 7.— 2004.— [P. 917-923] |
|---|---|
| Otros Autores: | , , , , , |
| Sumario: | Title screen Alkali metal halides NaF, KCl, and KBr sharply enhance the nitrating activity of sodium nitrate in acetic acid with respect to 9-methylcarbazole. In the presence of KI and KBr, both nitration and halogenation of the substrate occurs, while KCl and NaF promote only the nitration process. The results may be interpreted in terms of formation of the corresponding nitryl halides XNO2 (X = F, Cl, Br, I) whose structure and reactivity were examined in the framework of the density functional theory (DFT B3LYP/3-21G*). Режим доступа: по договору с организацией-держателем ресурса |
| Lenguaje: | inglés |
| Publicado: |
2004
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| Materias: | |
| Acceso en línea: | http://dx.doi.org/10.1023/B:RUJO.0000045178.33131.c2 |
| Formato: | Electrónico Capítulo de libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=647610 |
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| 200 | 1 | |a Halogenating and nitrating activity of reagents based on sodium nitrate and alkali metal halides in acetic acid |f V. D. Filimonov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 923 (22 tit.)] | ||
| 330 | |a Alkali metal halides NaF, KCl, and KBr sharply enhance the nitrating activity of sodium nitrate in acetic acid with respect to 9-methylcarbazole. In the presence of KI and KBr, both nitration and halogenation of the substrate occurs, while KCl and NaF promote only the nitration process. The results may be interpreted in terms of formation of the corresponding nitryl halides XNO2 (X = F, Cl, Br, I) whose structure and reactivity were examined in the framework of the density functional theory (DFT B3LYP/3-21G*). | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Russian Journal of Organic Chemistry |d 2001- | ||
| 463 | |t Vol. 40, iss. 7 |v [P. 917-923] |d 2004 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a reagents | |
| 610 | 1 | |a acetic acid | |
| 610 | 1 | |a alkali metals | |
| 610 | 1 | |a реагенты | |
| 610 | 1 | |a щелочные металлы | |
| 610 | 1 | |a уксусная кислота | |
| 701 | 1 | |a Filimonov |b V. D. |c Russian chemist |c Professor of the TPU |f 1945- |g Viktor Dmitrievich |3 (RuTPU)RU\TPU\pers\26423 |9 12127 | |
| 701 | 1 | |a Kulmanakova |b Yu. Yu. | |
| 701 | 1 | |a Yusubov |b M. S. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1961- |g Mekhman Suleiman-Ogly (Suleimanovich) |3 (RuTPU)RU\TPU\pers\31833 |9 15928 | |
| 701 | 1 | |a Perederina |b I. A. | |
| 701 | 1 | |a Ki-Whan Chi | |
| 701 | 1 | |a Poleshchuk |b O. Kh. |c chemist |c Professor-consultant of Yurga technological Institute of Tomsk Polytechnic University, Doctor of chemical sciences |f 1947- |g Oleg Khemovich |3 (RuTPU)RU\TPU\pers\31825 |9 15920 | |
| 801 | 2 | |a RU |b 63413507 |c 20160419 |g RCR | |
| 856 | 4 | |u http://dx.doi.org/10.1023/B:RUJO.0000045178.33131.c2 | |
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