Adsorption and catalytic properties of Co-Mo-Al₂O₃ catalysts and of their components in thiophene hydrodesulfurization reaction; Journal of Catalysis; Vol. 86, iss. 1
| Parent link: | Journal of Catalysis: Scientific Journal.— , 1962- Vol. 86, iss. 1.— 1984.— [P. 55-66] |
|---|---|
| Egile nagusia: | |
| Beste egile batzuk: | |
| Gaia: | Title screen The catalytic activities of Co-Mo-Al2O3 catalysts and of their components in the thiophene hydrodesulfurization reaction (HDS) were studied by a flow circulation technique. Catalysts in the oxidic form with CoMoO4 as the main phase are shown to possess the highest activity for the thiophene HDS reaction. Adsorption of H2, thiophene, and of their mixture on sulfided CoMoO4 and technical Co-Mo-Al2O3 catalysts was investigated by TPD. H2 is adsorbed both molecularily and dissociatively on the catalysts studied, while thiophene is molecularily adsorbed. Desorption activation energies for the different H2 and thiophene forms were measured. The thiophene HDS reaction involves high-temperature forms of adsorbed thiophene, while hydrogenation of unsaturated hydrocarbons (butenes) involves high-temperature forms of adsorbed hydrogen. A scheme of the thiophene HDS reaction on sulfided CoMoO4 and technical Co-Mo-Al2O3 catalysts is suggested on the basis of the results obtained. Режим доступа: по договору с организацией-держателем ресурса |
| Hizkuntza: | ingelesa |
| Argitaratua: |
1984
|
| Gaiak: | |
| Sarrera elektronikoa: | http://dx.doi.org/10.1016/0021-9517(84)90347-6 |
| Formatua: | Baliabide elektronikoa Liburu kapitulua |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=647485 |
MARC
| LEADER | 00000naa0a2200000 4500 | ||
|---|---|---|---|
| 001 | 647485 | ||
| 005 | 20250619145807.0 | ||
| 035 | |a (RuTPU)RU\TPU\network\12625 | ||
| 035 | |a RU\TPU\network\12624 | ||
| 090 | |a 647485 | ||
| 100 | |a 20160412d1984 k||y0rusy50 ba | ||
| 101 | 0 | |a eng | |
| 102 | |a US | ||
| 135 | |a drcn ---uucaa | ||
| 181 | 0 | |a i | |
| 182 | 0 | |a b | |
| 200 | 1 | |a Adsorption and catalytic properties of Co-Mo-Al₂O₃ catalysts and of their components in thiophene hydrodesulfurization reaction |f V. I. Erofeev, I. V. Kaletchits | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 66 (26 tit.)] | ||
| 330 | |a The catalytic activities of Co-Mo-Al2O3 catalysts and of their components in the thiophene hydrodesulfurization reaction (HDS) were studied by a flow circulation technique. Catalysts in the oxidic form with CoMoO4 as the main phase are shown to possess the highest activity for the thiophene HDS reaction. Adsorption of H2, thiophene, and of their mixture on sulfided CoMoO4 and technical Co-Mo-Al2O3 catalysts was investigated by TPD. H2 is adsorbed both molecularily and dissociatively on the catalysts studied, while thiophene is molecularily adsorbed. Desorption activation energies for the different H2 and thiophene forms were measured. The thiophene HDS reaction involves high-temperature forms of adsorbed thiophene, while hydrogenation of unsaturated hydrocarbons (butenes) involves high-temperature forms of adsorbed hydrogen. A scheme of the thiophene HDS reaction on sulfided CoMoO4 and technical Co-Mo-Al2O3 catalysts is suggested on the basis of the results obtained. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | 1 | |t Journal of Catalysis |o Scientific Journal |d 1962- | |
| 463 | 1 | |t Vol. 86, iss. 1 |v [P. 55-66] |d 1984 | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 700 | 1 | |a Erofeev |b V. I. |c specialist in the field of oil and gas business |c Professor of Tomsk Polytechnic University, Doctor of technical sciences |f 1946- |g Vladimir Ivanovich |3 (RuTPU)RU\TPU\pers\32197 |9 16197 | |
| 701 | 1 | |a Kaletchits |b I. V. | |
| 801 | 2 | |a RU |b 63413507 |c 20160414 |g RCR | |
| 850 | |a 63413507 | ||
| 856 | 4 | |u http://dx.doi.org/10.1016/0021-9517(84)90347-6 | |
| 942 | |c CF | ||