Simultaneous spectrophotometric determination of chromium(VI) and iron (III) by H-point standard addition method; IOP Conference Series: Materials Science and Engineering; Vol. 110 : Radiation-Thermal Effects and Processes in Inorganic Materials (RTEP2015)
| Parent link: | IOP Conference Series: Materials Science and Engineering Vol. 110 : Radiation-Thermal Effects and Processes in Inorganic Materials (RTEP2015).— 2016.— [012079, 5 p.] |
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| Özet: | Title screen In this work the possibility of simultaneous spectrophotometric determination of chromium (VI) and iron (III) in alloys with help of the mixed organic reagent (diphenylcarbazide and 1,10-phenanthroline) is studied. We have applied Н-point standard addition method to determine concentrations of chromium (VI) and iron (III) from the mixture. The pure signals of complexes of chromium (VI) with diphenylcarbazide and iron (III) with the 1,10-phenanthroline and their calibration plots are previously carried out. We established the possibility of simultaneous determination of chromium (VI) and iron (III) in the different concentration ranges by Н-point standard addition method. Correctness of determination of concentration by means of the offered technique is proved by "added-found" method for a series of mixtures with different ratios of concentration of chromium (VI) and iron (III). It is founded that the error of determination of concentration doesn't exceed 33 %.. Режим доступа: по договору с организацией-держателем ресурса |
| Dil: | İngilizce |
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2016
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| Online Erişim: | http://dx.doi.org/10.1088/1757-899X/110/1/012079 http://earchive.tpu.ru/handle/11683/18090 |
| Materyal Türü: | Elektronik Kitap Bölümü |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=647049 |
| Özet: | Title screen In this work the possibility of simultaneous spectrophotometric determination of chromium (VI) and iron (III) in alloys with help of the mixed organic reagent (diphenylcarbazide and 1,10-phenanthroline) is studied. We have applied Н-point standard addition method to determine concentrations of chromium (VI) and iron (III) from the mixture. The pure signals of complexes of chromium (VI) with diphenylcarbazide and iron (III) with the 1,10-phenanthroline and their calibration plots are previously carried out. We established the possibility of simultaneous determination of chromium (VI) and iron (III) in the different concentration ranges by Н-point standard addition method. Correctness of determination of concentration by means of the offered technique is proved by "added-found" method for a series of mixtures with different ratios of concentration of chromium (VI) and iron (III). It is founded that the error of determination of concentration doesn't exceed 33 %.. Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.1088/1757-899X/110/1/012079 |