Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane; Inorganic Chemistry Communications; Vol. 64

Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane; Inorganic Chemistry Communications; Vol. 64

Dettagli Bibliografici
Parent link:	Inorganic Chemistry Communications Vol. 64.— 2016.— [P. 23-26]
Ente Autore:	Национальный исследовательский Томский политехнический университет Институт физики высоких технологий Кафедра биотехнологии и органической химии
Altri autori:	Semitut E. Yu. Evgeny Yurjevich, Komarov V. Yu. Vladislav Yu., Filatov E. Yu. Evgeny Yu., Kuznetsova A. S. Anastasiya Sergeevna, Khlebnikov A. I. Andrey Ivanovich, Potapov A. S. Andrey Sergeevich
Riassunto:	Title screen Reaction between 1,1,2,2-tetra(pyrazol-1-yl)ethane (Pz4) and copper(II) nitrate in ethanol at room temperature and in solvothermal conditions (90 °C) lead to coordination polymers of two different structures. A ribbon-like coordination polymer {Cu2(μ2-NO3)2(H2O)4 μ′2-Pz4}n was formed at room temperature in which nitrate ions bind the monomeric units, while Pz4 ligands are responsible for cross-linking of {Cu(μ-NO3)} chains. At 90 °C linear 1D coordination polymer was formed, in which Pz4 ligands bridge copper ions that in addition bear two monodentate nitrate ions. Режим доступа: по договору с организацией-держателем ресурса
Lingua:	inglese
Pubblicazione:	2016
Soggetti:	электронный ресурс труды учёных ТПУ кристаллические структуры
Accesso online:	http://dx.doi.org/10.1016/j.inoche.2015.12.008
Natura:	Elettronico Capitolo di libro
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=646426

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