Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane; Inorganic Chemistry Communications; Vol. 64

Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane; Inorganic Chemistry Communications; Vol. 64

Detalhes bibliográficos
Parent link:Inorganic Chemistry Communications
Vol. 64.— 2016.— [P. 23-26]
Autor Corporativo: Национальный исследовательский Томский политехнический университет Институт физики высоких технологий Кафедра биотехнологии и органической химии
Outros Autores: Semitut E. Yu. Evgeny Yurjevich, Komarov V. Yu. Vladislav Yu., Filatov E. Yu. Evgeny Yu., Kuznetsova A. S. Anastasiya Sergeevna, Khlebnikov A. I. Andrey Ivanovich, Potapov A. S. Andrey Sergeevich
Resumo:Title screen
Reaction between 1,1,2,2-tetra(pyrazol-1-yl)ethane (Pz4) and copper(II) nitrate in ethanol at room temperature and in solvothermal conditions (90 °C) lead to coordination polymers of two different structures. A ribbon-like coordination polymer {Cu2(μ2-NO3)2(H2O)4 μ′2-Pz4}n was formed at room temperature in which nitrate ions bind the monomeric units, while Pz4 ligands are responsible for cross-linking of {Cu(μ-NO3)} chains. At 90 °C linear 1D coordination polymer was formed, in which Pz4 ligands bridge copper ions that in addition bear two monodentate nitrate ions.
Режим доступа: по договору с организацией-держателем ресурса
Idioma:inglês
Publicado em: 2016
Assuntos:
электронный ресурс
труды учёных ТПУ
кристаллические структуры
Acesso em linha:http://dx.doi.org/10.1016/j.inoche.2015.12.008
Formato: Recurso Eletrônico Capítulo de Livro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=646426

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