Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane; Inorganic Chemistry Communications; Vol. 64

Bibliografiset tiedot
Parent link:Inorganic Chemistry Communications
Vol. 64.— 2016.— [P. 23-26]
Yhteisötekijä: Национальный исследовательский Томский политехнический университет Институт физики высоких технологий Кафедра биотехнологии и органической химии
Muut tekijät: Semitut E. Yu. Evgeny Yurjevich, Komarov V. Yu. Vladislav Yu., Filatov E. Yu. Evgeny Yu., Kuznetsova A. S. Anastasiya Sergeevna, Khlebnikov A. I. Andrey Ivanovich, Potapov A. S. Andrey Sergeevich
Yhteenveto:Title screen
Reaction between 1,1,2,2-tetra(pyrazol-1-yl)ethane (Pz4) and copper(II) nitrate in ethanol at room temperature and in solvothermal conditions (90 °C) lead to coordination polymers of two different structures. A ribbon-like coordination polymer {Cu2(μ2-NO3)2(H2O)4 μ′2-Pz4}n was formed at room temperature in which nitrate ions bind the monomeric units, while Pz4 ligands are responsible for cross-linking of {Cu(μ-NO3)} chains. At 90 °C linear 1D coordination polymer was formed, in which Pz4 ligands bridge copper ions that in addition bear two monodentate nitrate ions.
Режим доступа: по договору с организацией-держателем ресурса
Kieli:englanti
Julkaistu: 2016
Aiheet:
Linkit:http://dx.doi.org/10.1016/j.inoche.2015.12.008
Aineistotyyppi: Elektroninen Kirjan osa
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=646426