Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane; Inorganic Chemistry Communications; Vol. 64
| Parent link: | Inorganic Chemistry Communications Vol. 64.— 2016.— [P. 23-26] |
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| Համատեղ հեղինակ: | |
| Այլ հեղինակներ: | , , , , , |
| Ամփոփում: | Title screen Reaction between 1,1,2,2-tetra(pyrazol-1-yl)ethane (Pz4) and copper(II) nitrate in ethanol at room temperature and in solvothermal conditions (90 °C) lead to coordination polymers of two different structures. A ribbon-like coordination polymer {Cu2(μ2-NO3)2(H2O)4 μ′2-Pz4}n was formed at room temperature in which nitrate ions bind the monomeric units, while Pz4 ligands are responsible for cross-linking of {Cu(μ-NO3)} chains. At 90 °C linear 1D coordination polymer was formed, in which Pz4 ligands bridge copper ions that in addition bear two monodentate nitrate ions. Режим доступа: по договору с организацией-держателем ресурса |
| Լեզու: | անգլերեն |
| Հրապարակվել է: |
2016
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| Խորագրեր: | |
| Առցանց հասանելիություն: | http://dx.doi.org/10.1016/j.inoche.2015.12.008 |
| Ձևաչափ: | Էլեկտրոնային Գրքի գլուխ |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=646426 |
| Ամփոփում: | Title screen Reaction between 1,1,2,2-tetra(pyrazol-1-yl)ethane (Pz4) and copper(II) nitrate in ethanol at room temperature and in solvothermal conditions (90 °C) lead to coordination polymers of two different structures. A ribbon-like coordination polymer {Cu2(μ2-NO3)2(H2O)4 μ′2-Pz4}n was formed at room temperature in which nitrate ions bind the monomeric units, while Pz4 ligands are responsible for cross-linking of {Cu(μ-NO3)} chains. At 90 °C linear 1D coordination polymer was formed, in which Pz4 ligands bridge copper ions that in addition bear two monodentate nitrate ions. Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.1016/j.inoche.2015.12.008 |