Self-Organized Nanostructured Ag/P2O5/SiO2 Material as a Catalyst for High-Temperature Selective Oxidation of Alcohols; Key Engineering Materials; Vol. 670 : Multifunctional Chemical Materials and Technologies
| Parent link: | Key Engineering Materials: Scientific Journal Vol. 670 : Multifunctional Chemical Materials and Technologies.— 2015.— [P. 126-132] |
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| Collectivité auteur: | |
| Autres auteurs: | , , , , , , |
| Résumé: | Title screen New type of Ag-containing nanostructured catalyst for high-temperature alcohol oxidation was developed on the basis of mesoporous SiO2 support. Active component (silver clusters/nanoparticles) stabilized by support surface and polyphosphate inside the pores. It was shown that Ag/P2O5/SiO2 catalyst provides high activity in the course of ethylene glycol oxidation to glyoxal at 500-600 °C. Formation of stable structure of catalyst during thermal treatment includes self-organization of mesoporous structure and chemical bonding of phosphate with silica. The catalyst treatment in red-ox conditions leads to reversible oxidation-reduction of silver and its redistribution from bulk to surface of the catalyst. Silver nanoparticles stabilized with silica-phosphate support are active species in the ethylene glycol oxidation into glyoxal. Режим доступа: по договору с организацией-держателем ресурса |
| Langue: | anglais |
| Publié: |
2015
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| Collection: | Chemical Materials and Technologies in Chemical Manufacturing |
| Sujets: | |
| Accès en ligne: | http://dx.doi.org/10.4028/www.scientific.net/KEM.670.126 |
| Format: | MixedMaterials Électronique Chapitre de livre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=646311 |