Historical records of organic matter supply and degradation status in the East Siberian Sea; Organic Geochemistry; Vol. 91

Xehetasun bibliografikoak
Parent link:Organic Geochemistry.— , 1977-
Vol. 91.— 2016.— [P. 16-30]
Egile korporatiboa: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра геологии и разведки полезных ископаемых (ГРПИ) Международная научно-образовательная лаборатория изучения углерода арктических морей (МНОЛ ИУАМ), Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра геологии и разведки полезных ископаемых (ГРПИ)
Beste egile batzuk: Broder L. Lisa, Tesi T. Tommaso, Andersson A. August, Eglinton T. I. Timothy, Semiletov I. P. Igor Petrovich, Dudarev O. V. Oleg Viktorovich, Roos P. Per, Gustafsson O. Orjan
Gaia:Title screen
Destabilization and degradation of permafrost carbon in the Arctic regions could constitute a positive feedback to climate change. A better understanding of its fate upon discharge to the Arctic shelf is therefore needed. In this study, bulk carbon isotopes as well as terrigenous and marine biomarkers were used to construct two centennial records in the East Siberian Sea. Differences in topsoil and Pleistocene Ice Complex Deposit permafrost concentrations, modeled using [б]13C and [б]14C, were larger between inner and outer shelf than the changes over time. Similarly, lignin-derived phenol and cutin acid concentrations differed by a factor of ten between the two stations, but did not change significantly over time, consistent with the dual-carbon isotope model. High molecular weight (HMW) n-alkane and n-alkanoic acid concentrations displayed a smaller difference between the two stations (factor of 3–6). By contrast, the fraction for marine OC drastically decreased during burial with a half-life of 19–27 years. Vegetation and degradation proxies suggested supply of highly degraded gymnosperm wood tissues. Lipid Carbon Preference Index (CPI) values indicated more extensively degraded HMW n-alkanes on the outer shelf with no change over time, whereas n-alkanoic acids appeared to be less degraded toward the core top with no large differences between the stations. Taken together, our results show larger across-shelf changes than down-core trends. Further investigation is required to establish whether the observed spatial differences are due to different sources for the two depositional settings or, alternatively, a consequence of hydrodynamic sorting combined with selective degradation during cross-shelf transport.
Режим доступа: по договору с организацией-держателем ресурса
Hizkuntza:ingelesa
Argitaratua: 2016
Gaiak:
Sarrera elektronikoa:http://dx.doi.org/10.1016/j.orggeochem.2015.10.008
Formatua: Baliabide elektronikoa Liburu kapitulua
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=646292

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320 |a [References: p. 29-30] 
330 |a Destabilization and degradation of permafrost carbon in the Arctic regions could constitute a positive feedback to climate change. A better understanding of its fate upon discharge to the Arctic shelf is therefore needed. In this study, bulk carbon isotopes as well as terrigenous and marine biomarkers were used to construct two centennial records in the East Siberian Sea. Differences in topsoil and Pleistocene Ice Complex Deposit permafrost concentrations, modeled using [б]13C and [б]14C, were larger between inner and outer shelf than the changes over time. Similarly, lignin-derived phenol and cutin acid concentrations differed by a factor of ten between the two stations, but did not change significantly over time, consistent with the dual-carbon isotope model. High molecular weight (HMW) n-alkane and n-alkanoic acid concentrations displayed a smaller difference between the two stations (factor of 3–6). By contrast, the fraction for marine OC drastically decreased during burial with a half-life of 19–27 years. Vegetation and degradation proxies suggested supply of highly degraded gymnosperm wood tissues. Lipid Carbon Preference Index (CPI) values indicated more extensively degraded HMW n-alkanes on the outer shelf with no change over time, whereas n-alkanoic acids appeared to be less degraded toward the core top with no large differences between the stations. Taken together, our results show larger across-shelf changes than down-core trends. Further investigation is required to establish whether the observed spatial differences are due to different sources for the two depositional settings or, alternatively, a consequence of hydrodynamic sorting combined with selective degradation during cross-shelf transport. 
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463 |t Vol. 91  |v [P. 16-30]  |d 2016 
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