CO[2] Sequestration by Natural Zeolite for Greenhouse Effect Control; Procedia Chemistry; Vol. 15 : Chemistry and Chemical Engineering in XXI century (CCE 2015)
| Parent link: | Procedia Chemistry Vol. 15 : Chemistry and Chemical Engineering in XXI century (CCE 2015).— 2015.— [P. 33-41] |
|---|---|
| Awdur Corfforaethol: | Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ) |
| Awduron Eraill: | Hernandez M. A. Miguel Angel, Pestryakov A. N. Aleksey Nikolaevich, Portillo R. Roberto, Salgado M. A. Martha, Rojas F. Fernando, Rubio E. Efrain, Ruiz S. Sinuhe, Petranovskii V. Vitalii |
| Crynodeb: | Title screen This paper describes the adsorption of CO[2] on pores in natural erionite exchanged with aqueous solutions of Na{+}, Mg{2+}, and Ca{2+} salts at different concentrations, variable time and temperature of treatment. Experimental data of CO[2] adsorption were treated by the Freundlich and Langmuir equations. Complementarily were evaluated standard adsorption energies and the degree of interaction of the gas with the zeolite; the evolution of isosteric heats of adsorption was analyzed. The exchange with Na{+} favors the creation of emergent pores thus causing an increase of the adsorption capacity for CO[2]. The presence of Na{+} at micropore entrances causes an increased adsorption into the nanocavities and on the external area of the ion-exchanged zeolites. The development of nanopores in erionite was evaluated through the Barrett-Joyner-Halenda and NLDFT methods. Depending on the conditions of the exchange treatment, Na{+} was found to be most favorable, well distributed, and accessible for N[2] adsorption. Режим доступа: по договору с организацией-держателем ресурса |
| Iaith: | Saesneg |
| Cyhoeddwyd: |
2015
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| Pynciau: | |
| Mynediad Ar-lein: | http://dx.doi.org/10.1016/j.proche.2015.10.006 http://earchive.tpu.ru/handle/11683/15082 |
| Fformat: | Electronig Pennod Llyfr |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=645299 |
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