Deliquescence: Hygroscopicity of Water-Soluble Crystalline Solids

Deliquescence: Hygroscopicity of Water-Soluble Crystalline Solids

Bibliographic Details
Parent link:Journal of Pharmaceutical Sciences
Vol. 104, iss. 11.— 2015.— [P. 3639-3652]
Main Author: Tereshchenko A. G. Anatoly Georgievich
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Научно-исследовательский институт высоких напряжений (НИИВН) Лаборатория № 7
Summary:Title screen
A thermodynamic approach to the description of hygroscopic properties of crystal-soluble solids is introduced. Isotherms of water vapor sorption by a pure substance and the products with a heterogeneous or homogeneous impurity are compared. Solubility diagrams of substances in water are used to evaluate the influence of impurities on the hygroscopic properties of the products. Evidence demonstrates that water vapor sorption by a chemical product below the hygroscopic point of a basic component is determined by heterogeneous impurities. The introduction of the term “a hygroscopically pure substance” removes inconsistencies between the experimental results related to water vapor sorption and abstract theorems. The paper discusses relevant publications, concerning hygroscopicity of soluble substances, where the impurities are ignored resulting in procedural and theoretical errors.
Published: 2015
Subjects:
электронный ресурс
труды учёных ТПУ
гигроскопичность
сорбция
воды
твердые тела
адсорбция
абсорбция
Online Access:http://dx.doi.org/10.1002/jps.24589
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=644683

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